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Q7.1:

Write IUPAC names of the following compounds:

Solution :

1. Analysis of Structure (i)

Structure provided: $CH_3 - CH_2 - CH(OH) - CH_2 - CH_2 - CH_3$

  • Longest Carbon Chain: The chain consists of 6 carbon atoms [Hexane derivative].
  • Functional Group Position: The hydroxyl ($-OH$) group is attached to the 3rd carbon atom.
  • Numbering: Numbering from the left gives the $-OH$ group position 3. Numbering from the right also gives it position 4. To minimize the locant, we use the left-to-right path [Per IUPAC Nomenclature Rules for Alcohols].

IUPAC Name: Hexan-3-ol

2. Analysis of Structure (ii)

Structure provided: $(CH_3)_2CH - CH(OH) - CH_2 - CH_3$

  • Expanded Form: $CH_3 - CH(CH_3) - CH(OH) - CH_2 - CH_3$
  • Longest Carbon Chain: The parent chain contains 5 carbon atoms [Pentane derivative].
  • Substituent: A methyl group ($-CH_3$) is present at the 4th position if numbered from the $-OH$ side, or the 2nd position if numbered from the left. Assigning the lowest locant to the functional group ($-OH$):
    • Right to Left: $OH$ at $C_2$, $CH_3$ at $C_4$.
    • Left to Right: $OH$ at $C_3$, $CH_3$ at $C_2$.
    Following the priority rule (Functional group gets the lowest possible locant), we select the chain where the $-OH$ group is at $C_2$.

IUPAC Name: 4-Methylpentan-2-ol

3. Analysis of Structure (iii)

Structure provided: $CH_3 - CH_2 - CH_2 - CH_2 - CH(OH) - CH_2 - CH_3$

  • Longest Carbon Chain: The chain contains 7 carbon atoms [Heptane derivative].
  • Functional Group Position: The $-OH$ group is at the 3rd carbon when numbering from the right.

IUPAC Name: Heptan-3-ol

4. Analysis of Structure (iv)

Structure provided: $CH_3 - C(CH_3)_2 - CH_2 - CH(OH) - CH_3$

  • Longest Carbon Chain: 5 carbons [Pentane].
  • Substituents: Two methyl groups at position 4.
  • Functional Group: Hydroxyl at position 2.

IUPAC Name: 4,4-Dimethylpentan-2-ol

Visual Representation of IUPAC Priority

C1 C2 C3 C4 C5 OH

Final Solution:

CompoundIUPAC Name
(i)Hexan-3-ol
(ii)4-Methylpentan-2-ol
(iii)Heptan-3-ol
(iv)4,4-Dimethylpentan-2-ol


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