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Q8.3(iii):
Draw the structure of the following compound. (iii) p-Methylbenzaldehyde

Solution :

Step 1: Analyzing the Molecular Components

The name p-Methylbenzaldehyde indicates a derivative of benzene where two functional groups are attached at specific positions:

  • Parent Structure: Benzaldehyde ($C_6H_5CHO$), which consists of a benzene ring bonded to a formyl group ($-CHO$).
  • Substituent: A methyl group ($-CH_3$).
  • Positional Descriptor: The prefix p- (para) specifies that the methyl group is located at the 4-position relative to the aldehyde group (the 1-position).

Step 2: Defining the Atomic Connectivity

In IUPAC nomenclature, the carbon atom of the aldehyde group attached to the benzene ring is assigned position 1. By para substitution, the methyl group is attached to the carbon diametrically opposite to the aldehyde group on the hexagonal benzene ring [Per IUPAC Nomenclature Rules for Aromatic Compounds].

Step 3: Structural Visualization

CHO CH₃

Step 4: Chemical Formula and Analysis

The molecular formula of p-Methylbenzaldehyde is derived by adding the atoms of the substituents to the benzene core ($C_6H_6$):

Component Contribution
Benzene Ring Core $C_6H_4$
Aldehyde Group ($-CHO$) $+C_1H_1O_1$
Methyl Group ($-CH_3$) $+C_1H_3$
Total Molecular Formula $C_8H_8O$

The structure consists of a benzene ring substituted at the 1 and 4 positions. The aldehyde carbon is $sp^2$ hybridized, exhibiting a planar geometry, which facilitates conjugation with the $\pi$-electron system of the benzene ring [Per Molecular Orbital Theory].

Final Solution: The structure of p-Methylbenzaldehyde (4-methylbenzaldehyde) is represented by a benzene ring having a $-CHO$ group at position 1 and a $-CH_3$ group at position 4, with the molecular formula $C_8H_8O$.


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