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Q9.3(b):
Fill in the blanks using the word(s) from the list appended with each statement: (b) Viscosity of gases . . . with temperature, whereas viscosity of liquids . . . with temperature (increases / decreases)

Solution :

Theoretical Foundation: Viscosity in Fluids

Viscosity is a measure of a fluid's internal resistance to flow, arising from the transfer of momentum between adjacent layers moving at different velocities [per the molecular kinetic theory]. The temperature dependence of viscosity differs fundamentally between gases and liquids due to the nature of their intermolecular interactions.

Step 1: Analyzing Gas Viscosity

In gases, molecules are in constant, random thermal motion. The viscosity arises primarily from the transfer of momentum via the collision of molecules between layers moving at different velocities. According to the kinetic theory of gases, the coefficient of viscosity $\eta$ is given by:

$\eta = \frac{1}{3} \rho \bar{v} \lambda$

Where:

  • $\rho$ is the density of the gas.
  • $\bar{v}$ is the average speed of gas molecules (where $\bar{v} \propto \sqrt{T}$).
  • $\lambda$ is the mean free path of the molecules.

[By the relation $\bar{v} \propto \sqrt{T}$], as temperature ($T$) increases, the average speed of the molecules increases. This leads to more frequent momentum exchange between layers. Consequently, the viscosity of gases increases with temperature.

Step 2: Analyzing Liquid Viscosity

In liquids, molecules are closely packed and subject to significant cohesive intermolecular forces. These forces create "potential barriers" that molecules must overcome to slide past one another. The viscosity of a liquid is essentially a manifestation of these cohesive forces.

As temperature increases, the kinetic energy of the liquid molecules increases, allowing them to overcome these intermolecular cohesive forces more easily [per the Boltzmann distribution law]. As the intermolecular attraction becomes less effective in hindering flow at higher thermal energies, the internal friction decreases. Thus, the viscosity of liquids decreases with temperature.

Visual Representation: Temperature vs. Viscosity Trends

Temperature (T) Viscosity (η) Gases Liquids

Step 3: Synthesis of Results

Based on the physical mechanisms described above, the statement is completed as follows:

Fluid Type Trend with Increasing Temperature
Gases Increases
Liquids Decreases

Final Solution: Viscosity of gases increases with temperature, whereas viscosity of liquids decreases with temperature.


More Questions from Class 11 Physics Mechanical Properties of Fluids EXERCISES


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