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Q10.2(b):
Explain why (b) Water on a clean glass surface tends to spread out while mercury on the same surface tends to form drops. (Put differently, water wets glass while mercury does not.)

Solution :

1. Theoretical Foundation: The Mechanics of Adhesion and Cohesion

The wetting behavior of a liquid on a solid surface is determined by the competition between two specific molecular forces:

  • Cohesive Forces ($F_c$): The intermolecular forces of attraction between molecules of the same substance.
  • Adhesive Forces ($F_a$): The intermolecular forces of attraction between molecules of different substances (in this case, the liquid molecules and the glass surface molecules).

[Per the Young-Dupré equation and the concept of Surface Tension, the equilibrium shape of a drop is governed by the contact angle $\theta$.]

2. Comparative Analysis of Intermolecular Dynamics

Characteristic Water-Glass Interaction Mercury-Glass Interaction
Dominant Force $F_a > F_c$ $F_c > F_a$
Contact Angle ($\theta$) Acute ($\theta < 90^\circ$) Obtuse ($\theta > 90^\circ$)
Surface Result Spreading (Wetting) Droplet Formation (Non-wetting)

3. Mathematical Logic of Surface Energy

The shape of the liquid interface minimizes the total surface energy of the system. The total energy $E$ is given by:

$E = \gamma_{sl} A_{sl} + \gamma_{sg} A_{sg} + \gamma_{lg} A_{lg}$

Where $\gamma$ represents the interfacial tension between Solid-Liquid ($sl$), Solid-Gas ($sg$), and Liquid-Gas ($lg$).

[By the Principle of Minimum Potential Energy]:

  • For water, the adhesion to glass is strong enough to reduce the energy of the solid-liquid interface effectively, causing the liquid to maximize the surface area of contact, thus spreading out.
  • For mercury, the cohesive forces within the mercury atoms are significantly stronger than the adhesive force to the glass. To minimize energy, the mercury atoms maximize their contact with each other (forming a sphere, the shape with the minimum surface area for a given volume) and minimize contact with the glass, resulting in bead formation.

4. Visual Representation of Contact Angles

Water (Wetting) θ < 90° Mercury (Non-Wetting) θ > 90°

5. Conclusion

The wetting of a surface is a function of the contact angle $\theta$. When $F_a > F_c$, the contact angle is acute, leading to wetting. When $F_c > F_a$, the contact angle is obtuse, leading to the formation of a spherical drop to minimize surface area and energy.

Final Solution: Water spreads on a clean glass surface because the adhesive forces between water molecules and glass molecules are stronger than the cohesive forces between water molecules. Conversely, mercury forms drops because the cohesive forces between mercury atoms are far stronger than the adhesive forces between mercury and glass.


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