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Q10.3(b):
Fill in the blanks using the word(s) from the list appended with each statement: (b) Viscosity of gases . . . with temperature, whereas viscosity of liquids . . . with temperature (increases / decreases)

Solution :

Step 1: Analyzing Viscosity in Fluids

Viscosity is defined as the internal friction or the resistance to flow offered by a fluid. The physical origin of viscosity differs fundamentally between gases and liquids, leading to divergent dependencies on temperature.

Step 2: Viscosity of Gases

In gases, molecules move randomly with high kinetic energy. Viscosity arises due to the transport of momentum between different layers of the gas moving at different velocities. As temperature ($T$) increases, the average speed ($v_{avg}$) of gas molecules increases, where $v_{avg} \propto \sqrt{T}$ [Per the Kinetic Theory of Gases]. This higher molecular motion enhances the rate of momentum exchange between layers, thereby increasing the internal friction.

Consequently, the coefficient of viscosity ($\eta$) of gases increases with an increase in temperature.

Step 3: Viscosity of Liquids

In liquids, molecules are in close proximity, and viscosity is primarily governed by strong intermolecular cohesive forces. The liquid layers can slide past each other only if they overcome these cohesive barriers. As temperature increases, the kinetic energy of the molecules increases, which allows them to overcome these intermolecular attractions more easily [Per the Maxwell-Boltzmann Distribution and intermolecular force analysis]. This reduction in cohesive resistance leads to a decrease in viscosity.

Consequently, the coefficient of viscosity ($\eta$) of liquids decreases with an increase in temperature.

Step 4: Comparative Summary

Fluid State Dominant Mechanism Effect of Temperature ($\uparrow T$)
Gases Momentum transport via molecular collisions Viscosity Increases
Liquids Intermolecular cohesive forces Viscosity Decreases

Step 5: Visual Representation of Viscosity Trend

Temperature (T) Viscosity (η) Gases Liquids

Final Solution: Viscosity of gases increases with temperature, whereas viscosity of liquids decreases with temperature.


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