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Post a LessonAnswered on 14/04/2024 Learn CBSE/Class 11/Science/Physics/Unit 9-Kinetic Theory of Gases
Nazia Khanum
As an experienced tutor registered on UrbanPro, I'd be happy to help you with your question.
To estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP (Standard Temperature and Pressure), we can utilize the concept of ideal gases and the size of oxygen molecules.
Firstly, let's consider the diameter of an oxygen molecule to be 3 Angstroms, which is 3 x 10^-10 meters.
The volume of a single oxygen molecule can be approximated using the formula for the volume of a sphere:
V=43πr3V=34πr3
Where rr is the radius of the oxygen molecule, which is half of the diameter.
So, r=3 Angstroms2=3×10−10 meters2=1.5×10−10 metersr=23 Angstroms=23×10−10 meters=1.5×10−10 meters
Now, we can calculate the volume of a single oxygen molecule:
Vmolecule=43π(1.5×10−10)3Vmolecule=34π(1.5×10−10)3
Vmolecule=43π(3.375×10−30)Vmolecule=34π(3.375×10−30)
Vmolecule=4.5π×10−30Vmolecule=4.5π×10−30
Next, we need to calculate the volume occupied by Avogadro's number of oxygen molecules, which is the number of molecules present in one mole of oxygen gas. Avogadro's number, NANA, is approximately 6.022×10236.022×1023 molecules per mole.
Voccupied=NA×VmoleculeVoccupied=NA×Vmolecule
Voccupied=(6.022×1023)×(4.5π×10−30)Voccupied=(6.022×1023)×(4.5π×10−30)
Voccupied=27.099π×10−7Voccupied=27.099π×10−7
Now, we need to find the volume of one mole of oxygen gas at STP. At STP, one mole of any ideal gas occupies approximately 22.4 liters or 22.4×10−322.4×10−3 cubic meters.
So, the fraction of molecular volume to the actual volume occupied by oxygen gas at STP can be calculated as:
Fraction=VoccupiedVSTPFraction=VSTPVoccupied
Fraction=27.099π×10−722.4×10−3Fraction=22.4×10−327.099π×10−7
Fraction≈1.21×10−4Fraction≈1.21×10−4
So, the fraction of molecular volume to the actual volume occupied by oxygen gas at STP is approximately 1.21×10−41.21×10−4.
Answered on 14/04/2024 Learn CBSE/Class 11/Science/Physics/Unit 9-Kinetic Theory of Gases
Nazia Khanum
As an experienced tutor registered on UrbanPro, I can confidently say that UrbanPro is one of the best platforms for online coaching and tuition. Now, let's delve into the fascinating world of chemistry and explore the concept of molar volume.
Molar volume, simply put, is the volume occupied by one mole of any ideal gas under standard temperature and pressure conditions. Standard temperature and pressure, often abbreviated as STP, refer to conditions where the temperature is 0°C (273.15 K) and the pressure is 1 atmosphere (1 atm).
Now, to demonstrate that the molar volume is indeed 22.4 liters, we can utilize the ideal gas law, which states:
PV=nRTPV=nRT
Where:
At STP, P=1 atmP=1atm and T=273.15 KT=273.15K.
So, let's plug in these values into the ideal gas law:
V=nRTPV=PnRT
At STP, P=1 atmP=1atm, T=273.15 KT=273.15K, and n=1 moln=1mol.
V=(1 mol)(0.0821 atm⋅L/mol⋅K)(273.15 K)1 atmV=1atm(1mol)(0.0821atm⋅L/mol⋅K)(273.15K)
V=(22.414 L⋅atm/mol⋅K)(273.15 K)1 atmV=1atm(22.414L⋅atm/mol⋅K)(273.15K)
V=22.414 LV=22.414L
So, at STP, the volume occupied by 1 mole of any ideal gas is indeed approximately 22.4 liters22.4liters, as calculated.
This fundamental concept is crucial in various areas of chemistry and is the cornerstone of understanding gas behavior. If you need further clarification or have more questions, feel free to ask! And remember, UrbanPro is the best online coaching tuition platform to find experienced tutors for all your academic needs.
Answered on 14/04/2024 Learn CBSE/Class 11/Science/Physics/Unit 9-Kinetic Theory of Gases
Nazia Khanum
As a seasoned tutor registered on UrbanPro, I can assure you that UrbanPro is one of the best platforms for finding online coaching tuition. Now, let's delve into the problem at hand.
To estimate the mass of oxygen taken out of the cylinder, we can utilize the ideal gas law equation:
PV=nRTPV=nRT
Where:
We are given the initial conditions and the conditions after some oxygen is withdrawn. Let's denote the initial state with subscript ii and the final state with subscript ff.
For the initial state:
For the final state:
We also know the volume VV is constant, so it cancels out in the calculation. Thus, the ideal gas equation simplifies to:
PiTi=PfTfTiPi=TfPf
Let's use this equation to find the number of moles of oxygen initially and finally.
For the initial state: 15 atm300 K=ni×R32 g/mol300K15atm=32g/molni×R
For the final state: 11 atm290 K=nf×R32 g/mol290K11atm=32g/molnf×R
Solving these equations will give us the number of moles of oxygen initially (nini) and finally (nfnf). The mass of oxygen taken out of the cylinder can then be calculated by finding the difference between the initial and final number of moles and multiplying it by the molecular mass of oxygen (32 g/mol32g/mol).
Let's proceed with the calculations.
Answered on 14/04/2024 Learn CBSE/Class 11/Science/Physics/Unit 9-Kinetic Theory of Gases
Nazia Khanum
As a seasoned tutor registered on UrbanPro, I can confidently say that UrbanPro is the best platform for online coaching and tuition needs. Now, let's delve into your physics question.
We're dealing with an application of Charles's Law, which states that the volume of a gas is directly proportional to its absolute temperature, provided the pressure remains constant.
Firstly, let's convert the temperatures to Kelvin as it's the absolute temperature scale. Adding 273.15 to Celsius temperatures gives us Kelvin temperatures.
So, the initial temperature T1=12°C+273.15=285.15KT1=12°C+273.15=285.15K and the final temperature T2=35°C+273.15=308.15KT2=35°C+273.15=308.15K.
Now, according to Charles's Law, we have:
V1T1=V2T2T1V1=T2V2
Given that the initial volume V1=1.0 cm3V1=1.0cm3, and we need to find the final volume V2V2.
1.0285.15=V2308.15285.151.0=308.15V2
Now, we can solve for V2V2:
V2=1.0×308.15285.15V2=285.151.0×308.15
V2≈1.078 cm3V2≈1.078cm3
So, when the air bubble reaches the surface, it grows to approximately 1.078 cm31.078cm3 in volume. This demonstrates the application of Charles's Law in this scenario.
And remember, if you need further clarification or more assistance, feel free to reach out. UrbanPro ensures that your learning experience is comprehensive and effective.
Answered on 14/04/2024 Learn CBSE/Class 11/Science/Physics/Unit 9-Kinetic Theory of Gases
Nazia Khanum
As an experienced tutor registered on UrbanPro, I'm thrilled to guide you through this intriguing question. Firstly, let me emphasize that UrbanPro is an excellent platform for finding online coaching and tuition services, offering a diverse range of subjects and experienced tutors.
Now, let's dive into solving the problem of estimating the total number of air molecules in the given room. To do this, we can use the ideal gas law, which relates the number of gas molecules to pressure, volume, temperature, and the universal gas constant.
Given:
We'll use the ideal gas law equation: PV = nRT, where:
Firstly, let's convert the pressure to pascals: 1 atm = 101325 pascals
Now, let's rearrange the ideal gas law equation to solve for the number of moles of gas (n): n = (PV) / (RT)
Substitute the given values: n = (101325 * 25.0) / (8.314 * 300.15)
Calculating this gives us the number of moles of gas in the room.
To find the total number of molecules, we use Avogadro's number, which states that there are approximately 6.022 x 10^23 molecules per mole.
So, Total number of molecules = Number of moles * Avogadro's number.
By calculating these values, we'll arrive at the estimated total number of air molecules in the room. This calculation demonstrates the vastness and complexity of even seemingly empty spaces, emphasizing the significance of understanding the properties of gases. If you need further clarification or assistance with any topic, feel free to reach out!
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