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Q12.4:
The ground state energy of hydrogen atom is –13.6 eV. What are the kinetic and potential energies of the electron in this state?

Solution :

Step 1: Theoretical Foundation of Hydrogen Atom Energetics

According to the Bohr model of the hydrogen atom, the total energy ($E$), kinetic energy ($K$), and potential energy ($U$) of an electron in a stationary orbit are related to the electrostatic interaction between the nucleus (proton) and the orbiting electron [Per the Coulombic Law and Virial Theorem].

The total energy is defined as the sum of kinetic and potential energies:

$E = K + U$

From the virial theorem for a system under an inverse-square law force, we establish the following relationships:

  • $K = -E$
  • $U = 2E$

Step 2: Calculation of Kinetic Energy ($K$)

Given the ground state energy $E = -13.6 \text{ eV}$.

Using the derived relation $K = -E$:

$K = -(-13.6 \text{ eV})$

$K = 13.6 \text{ eV}$

[Justification: The kinetic energy must be positive as it represents the work done to bring the electron from rest to its orbital velocity].

Step 3: Calculation of Potential Energy ($U$)

Using the derived relation $U = 2E$:

$U = 2 \times (-13.6 \text{ eV})$

$U = -27.2 \text{ eV}$

[Justification: The negative sign indicates that the electron is in a bound state within the electrostatic potential well of the nucleus].

Visual Representation of Energy States

E = -13.6 eV Ground State (n=1) E Total Energy

Summary of Energetic Parameters

Parameter Value (eV)
Total Energy ($E$) $-13.6 \text{ eV}$
Kinetic Energy ($K$) $+13.6 \text{ eV}$
Potential Energy ($U$) $-27.2 \text{ eV}$

Final Solution: The kinetic energy of the electron in the ground state is 13.6 eV, and the potential energy is -27.2 eV.


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