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Q12.6(b):
(b) Calculate the orbital period in each of these levels.

Solution :

Step 1: Theoretical Foundation for Orbital Period

According to the Bohr model of the atom, the angular velocity $\omega$ of an electron in a stable orbit is related to the principal quantum number $n$. The orbital period $T$ is defined as the time taken for one complete revolution: $T = \frac{2\pi}{\omega}$.

From the derivation of the Bohr radius ($r_n$) and the velocity ($v_n$), we know that $v_n = \frac{v_1}{n}$ and $r_n = n^2 r_1$. Since $\omega = \frac{v_n}{r_n}$, we substitute the expressions:

$\omega_n = \frac{v_1/n}{n^2 r_1} = \frac{v_1}{n^3 r_1} = \frac{\omega_1}{n^3}$

Thus, the orbital period $T_n$ is given by: $T_n = \frac{2\pi}{\omega_1/n^3} = T_1 \cdot n^3$, where $T_1$ is the period of the ground state ($n=1$). [Per Bohr’s Postulates of Quantization]

Step 2: Calculating Ground State Period ($T_1$)

For the hydrogen atom, the velocity in the first orbit is $v_1 \approx 2.18 \times 10^6 \text{ m/s}$ and the Bohr radius is $r_1 \approx 0.529 \times 10^{-10} \text{ m}$.

The ground state angular frequency $\omega_1$ is: $\omega_1 = \frac{v_1}{r_1} = \frac{2.18 \times 10^6}{0.529 \times 10^{-10}} \approx 4.12 \times 10^{16} \text{ rad/s}$

Therefore, the ground state period $T_1$ is: $T_1 = \frac{2\pi}{\omega_1} = \frac{2 \times 3.14159}{4.12 \times 10^{16}} \approx 1.52 \times 10^{-16} \text{ s}$

Step 3: Calculating Periods for Higher Energy Levels

Using the relation $T_n = T_1 \cdot n^3$, we calculate the periods for $n=1, 2, 3$:

Quantum Number ($n$) Calculation ($1.52 \times 10^{-16} \times n^3$) Orbital Period ($T_n$)
$n=1$ $1.52 \times 10^{-16} \times 1$ $1.52 \times 10^{-16} \text{ s}$
$n=2$ $1.52 \times 10^{-16} \times 8$ $1.22 \times 10^{-15} \text{ s}$
$n=3$ $1.52 \times 10^{-16} \times 27$ $4.10 \times 10^{-15} \text{ s}$

Visualization of Orbital Expansion

Nucleus n=1 n=2 n=3

Final Solution: The orbital periods for $n=1, 2,$ and $3$ are $1.52 \times 10^{-16} \text{ s}$, $1.22 \times 10^{-15} \text{ s}$, and $4.10 \times 10^{-15} \text{ s}$ respectively.


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