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Q12.1(b):
Choose the correct alternative from the clues given at the end of the each statement: In the ground state of .......... electrons are in stable equilibrium, while in .......... electrons always experience a net force.

Solution :

Step 1: Establishing the Theoretical Foundation

To analyze the equilibrium of electrons in atomic models, we must evaluate the force vectors acting upon them. According to Classical Electromagnetic Theory (specifically Maxwell’s equations), an accelerated charge must radiate energy. If an electron were in a "stable equilibrium," it would imply a state where the net force is zero and no energy radiation occurs, preventing the collapse of the atom. In contrast, any orbit characterized by constant change in velocity (acceleration) results in a non-zero net force.

Step 2: Analyzing J.J. Thomson's Plum Pudding Model

In the Thomson model, the positive charge is distributed uniformly throughout the sphere, and the electron is embedded within it. When the electron is displaced from its equilibrium position at the center, the positive charge distribution exerts a restoring force proportional to the displacement ($F = -kx$). [By Hooke's Law and Electrostatic Force Analysis]. At the center, the net force is zero, representing a position of stable equilibrium.

Step 3: Analyzing the Rutherford/Bohr Planetary Model

In the planetary model, electrons revolve around the nucleus in circular orbits. The force acting on the electron is the centripetal force provided by the electrostatic Coulomb force ($F_c = \frac{1}{4\pi\epsilon_0} \frac{Ze^2}{r^2}$). Since the electron is undergoing circular motion, its velocity vector is constantly changing direction. [By Newton’s Second Law of Motion ($F = ma$)], a change in velocity implies a net force directed toward the center of the orbit. Therefore, in the planetary model, the electron is never in equilibrium.

Step 4: Comparative Data Table

Model Force Status Equilibrium Type
Thomson (Plum Pudding) Zero (at center) Stable Equilibrium
Rutherford/Bohr Non-Zero (Centripetal) Dynamic (Accelerated)

Step 5: Visual Representation of Force Vectors

Thomson Model Rutherford Model

Step 6: Conclusion based on Clues

The first blank refers to the state where the electron is held by a restoring force in a static potential, characteristic of the Thomson model. The second blank refers to the state of constant acceleration in an orbital path, characteristic of the Rutherford model.

Final Solution: In the ground state of Thomson model electrons are in stable equilibrium, while in Rutherford model electrons always experience a net force.


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