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Q12.3:
A difference of 2.3 eV separates two energy levels in an atom. What is the frequency of radiation emitted when the atom make a transition from the upper level to the lower level?

Solution :

Given Variables & Initial Setup

To determine the frequency of the emitted radiation during an electronic transition, we identify the following parameters provided by the problem:

  • Energy difference between the two levels: $\Delta E = 2.3 \text{ eV}$
  • Planck's constant: $h \approx 6.626 \times 10^{-34} \text{ J}\cdot\text{s}$
  • Elementary charge (conversion factor): $1 \text{ eV} = 1.602 \times 10^{-19} \text{ J}$

Step 1: Conversion of Energy to SI Units

The energy difference must be expressed in Joules ($\text{J}$) to maintain consistency with the SI units of Planck’s constant. [Per the definition of the electronvolt as a unit of energy].

$\Delta E (\text{in Joules}) = 2.3 \text{ eV} \times (1.602 \times 10^{-19} \text{ J/eV})$

$\Delta E = 3.6846 \times 10^{-19} \text{ J}$

Step 2: Theoretical Foundation of Emission Frequency

According to the Bohr postulate for atomic transitions, the frequency ($\nu$) of the emitted photon is directly proportional to the energy difference between the two states. [Per the Bohr Frequency Condition: $\Delta E = h\nu$].

Rearranging for frequency ($\nu$):

$\nu = \frac{\Delta E}{h}$

Step 3: Numerical Calculation

Substituting the values calculated in Step 1 and the known constant for Planck's constant:

$\nu = \frac{3.6846 \times 10^{-19} \text{ J}}{6.626 \times 10^{-34} \text{ J}\cdot\text{s}}$

$\nu \approx 0.55608 \times 10^{15} \text{ Hz}$

$\nu \approx 5.56 \times 10^{14} \text{ Hz}$

Upper Level ($E_2$) Lower Level ($E_1$) $\Delta E = 2.3 \text{ eV}$ $\nu \approx 5.56 \times 10^{14} \text{ Hz}$

Analytical Summary

The transition results in the release of a photon with frequency $\nu$. By applying the relationship $\nu = \frac{\Delta E}{h}$, we establish that the energy gap of $2.3 \text{ eV}$ corresponds to the visible spectrum region (specifically green-yellow light).

Final Solution: The frequency of the emitted radiation is $5.56 \times 10^{14} \text{ Hz}$.


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