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Q11:
Three water samples namely river water, untreated sewage water and secondary effluent discharged from a sewage treatment plant were subjected to BOD test. The samples were labelled \(A\), \(B\) and \(C\); but the laboratory attendant did not note which was which. The BOD values of the three samples \(A\), \(B\) and \(C\) were recorded as 20mg/L, 8mg/L and 400mg/L, respectively. Which sample of the water is most polluted? Can you assign the correct label to each assuming the river water is relatively clean?

Solution :

Theoretical Foundation: Biochemical Oxygen Demand (BOD)

Biochemical Oxygen Demand (BOD) refers to the amount of oxygen that would be consumed if all the organic matter in one liter of water were oxidized by bacteria. [Per the standard principles of environmental microbiology, BOD is an inverse indicator of water quality].

  • High BOD: Indicates high levels of organic pollutants, leading to increased microbial activity and subsequent oxygen depletion.
  • Low BOD: Indicates cleaner water with lower concentrations of organic nutrients.

Data Analysis & Comparative Tabulation

Sample Label BOD Value ($mg/L$) Water Quality Interpretation
$A$ $20$ Treated/Secondary Effluent
$B$ $8$ Clean (River Water)
$C$ $400$ Highly Polluted (Untreated Sewage)

Step 1: Identifying the Most Polluted Sample

Pollution potential is directly proportional to the organic load present in the sample. Sample $C$, possessing a BOD value of $400\ mg/L$, represents the highest concentration of organic matter requiring microbial decomposition. [Scientific Axiom: The rate of aerobic respiration in water is limited by the availability of dissolved oxygen; hence, a high BOD value signifies a high capacity for oxygen depletion].

Step 2: Assignment of Labels Based on Environmental Metrics

To assign the samples, we follow the established hierarchy of pollution levels:

  1. River Water: Typically the cleanest in this set, corresponding to the lowest BOD. Therefore, Sample $B$ ($8\ mg/L$) is the River Water.
  2. Secondary Effluent: Represents water that has undergone primary and secondary biological treatment, reducing the BOD significantly from its raw state. Sample $A$ ($20\ mg/L$) fits this category.
  3. Untreated Sewage: Contains high concentrations of organic pollutants, requiring the highest oxygen demand. Sample $C$ ($400\ mg/L$) is the Untreated Sewage.
B A C Water Samples by Pollution Intensity (BOD) BOD (mg/L)

Final Solution: Sample $C$ is the most polluted. The labels are: Sample $B$ = River Water ($8\ mg/L$), Sample $A$ = Secondary Effluent ($20\ mg/L$), and Sample $C$ = Untreated Sewage ($400\ mg/L$).


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