Calculate the enthalpy change for the process CCl4(g) → C(g) + 4 Cl(g) and calculate bond enthalpy of C – Cl in CCl4(g). ∆vapH(CCl4) = 30.5 kJ mol–1. ∆f H (CCl4) = –135.5 kJ mol–1. ∆aH (C) = 715.0 kJ mol–1 , where ∆aHis enthalpy of atomisation ∆aH (Cl2) = 242 kJ mol–1

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The chemical equations implying to the given values of enthalpies are: ΔvapHθ = 30.5 kJ mol–1 ΔaHθ = 715.0 kJ mol–1 ΔaHθ = 242 kJ mol–1 ΔfH = –135.5 kJ mol–1 Enthalpy change for the given process can be calculated using the following...
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The chemical equations implying to the given values of enthalpies are: ΔvapHθ = 30.5 kJ mol–1 ΔaHθ = 715.0 kJ mol–1 ΔaHθ = 242 kJ mol–1 ΔfH = –135.5 kJ mol–1 Enthalpy change for the given process can be calculated using the following algebraic calculations as: Equation (ii) + 2 × Equation (iii) – Equation (i) – Equation (iv) ΔH = ΔaHθ(C) + 2ΔaHθ (Cl2) – ΔvapHθ – ΔfH = (715.0 kJ mol–1) + 2(242 kJ mol–1) – (30.5 kJ mol–1) – (–135.5 kJ mol–1) ΔH = 1304 kJ mol–1 Bond enthalpy of C–Cl bond in CCl4 (g) = 326 kJ mol–1 read less
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