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The following data were obtained during the first order thermal decomposition of \(SO_{2}Cl_{2}\) at a constant volume. \(SO_{2}Cl_{2}(g) \rightarrow SO_{2}(g) + Cl_{2}(g)\)

Calculate the rate of the reaction when total pressure is 0.65 atm.
The rate constant for the decomposition of \(N_{2}O_{5}\) at various temperatures is given below:

Draw a graph between \(ln k\) and \(1/T\) and calculate the values of \(A\) and \(E_{a}\). Predict the rate constant at 30° and 50°C.
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