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Q3.34:
Which of the following statements related to the modern periodic table is incorrect?

Solution :

Analysis of Statements Regarding the Modern Periodic Table

To determine the incorrect statement, we must evaluate the fundamental principles governing the Modern Periodic Table, based on the Modern Periodic Law: "The physical and chemical properties of the elements are a periodic function of their atomic numbers."

Step 1: Evaluation of Core Periodic Trends and Structural Logic

The Modern Periodic Table organizes elements into $18$ vertical columns (groups) and $7$ horizontal rows (periods). The electronic configuration determines the placement of elements.

Statement Category Scientific Principle Verification
Group Structure Elements in the same group have the same valence shell electronic configuration. Correct [Per the Aufbau Principle].
Atomic Number The table is arranged in increasing order of atomic number ($Z$). Correct [Per Moseley’s Experiment].
$p$-block elements The $p$-block consists of elements where the last electron enters the $np$ orbital. Correct.

Step 2: Identification of Common Fallacies

Commonly tested incorrect statements regarding the periodic table include:

  • Fallacy 1: "The $d$-subshell is filled in the $p$-block elements." (Correction: The $d$-subshell is filled in transition elements/d-block).
  • Fallacy 2: "Elements in a period have identical properties." (Correction: Properties change gradually due to increasing effective nuclear charge $Z_{eff}$).
  • Fallacy 3: "The number of elements in each period is constant." (Correction: The number of elements follows the $2n^2$ rule, where $n$ is the principal quantum number, resulting in $2, 8, 8, 18, 18, 32, 32$ elements).

Step 3: Visual Representation of Periodic Block Distribution

s-block d-block p-block f-block (Lanthanoids/Actinoids)

Step 4: Conclusion on Incorrect Statements

Any statement suggesting that the properties of elements are periodic functions of atomic mass is categorically incorrect [Per the failure of Mendeleev's periodic law to account for isotopes]. Furthermore, statements claiming that the $f$-block elements represent the transition metals are scientifically inaccurate, as the $f$-block elements are specifically termed Inner Transition Elements.

Final Solution: Statements asserting that the modern periodic table is based on atomic mass rather than atomic number, or that $d$-block elements are not transition elements, are incorrect. The fundamental basis remains the atomic number ($Z$), which dictates the periodicity of electronic configuration.


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