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Q3.27(d):
Use the periodic table to answer the following questions. (d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.

Solution :

Analytical Framework: Categorization of Group 17 Elements

To identify the group containing metals, non-metals, liquids, and gases at standard room temperature ($298\text{ K}$), we must examine the properties of elements within the Periodic Table columns, specifically focusing on the Group 17 elements, known as the Halogens.

Step 1: Systematic Breakdown of Group 17 Constituents

Group 17 (Halogens) consists of elements that exhibit a wide range of physical states and metallic/non-metallic character due to the gradual increase in atomic size and van der Waals forces as one descends the group.

Element Symbol Physical State ($298\text{ K}$) Classification
Fluorine $F$ Gas Non-metal
Chlorine $Cl$ Gas Non-metal
Bromine $Br$ Liquid Non-metal
Iodine $I$ Solid Non-metal
Astatine $At$ Solid Metalloid (Transitioning to Metal)
Tennessine $Ts$ Solid Metal

Step 2: Verification of Criteria

The query requires a group containing:

  • Metal: Tennessine ($Ts$) resides in the metal category.
  • Non-metal: Fluorine ($F$), Chlorine ($Cl$), Bromine ($Br$), and Iodine ($I$) are characteristic non-metals.
  • Liquid: Bromine ($Br$) exists as a diatomic liquid at room temperature.
  • Gas: Fluorine ($F$) and Chlorine ($Cl$) exist as diatomic gases.

[Per the Periodic Law and trend of atomic radii, as the atomic number ($Z$) increases within Group 17, the atomic size increases, weakening the inter-molecular forces for light elements (gases) and strengthening the metallic character in heavier transactinide elements].

Visual Representation of Group 17 State Distribution

F, Cl (Gas) Br (Liquid) I, At (Solid) Ts (Metal) Progression of Physical State (Group 17)

Final Solution: The group that contains metals, non-metals, liquids, and gases at room temperature is Group 17 (the Halogen group, including the synthetic element Tennessine).


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