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Class 12 Organic Chemistry - Assigning R And S Configurations.

Nidhi
29/05/2017 0 0

Configuration is the relative position of the atoms in amolecule that can be arranged / changed exclusively by cleaving and forming new chemical bonds.

Steps to assign configurations:

Follow the direction of the remaining 3 priorities from highest to lowest priority (lowest to highest number, 1 < 2 < 3). A counterclockwise direction is an S (Latin for sinister, left) configuration. A clockwise direction is an R (Latin for rectus, right) configuration.

Approach:

According to the molecular weight of the attached groups in the ascending order, we no. 1, 2, 3, 4. If the numbers are not arranged in a particlar order clockwise or anticlockwise, we interchange the 2 groups so that the numbers can be arranged in increasing order clockwise or anticlockwise.

Answer: All the above compounds have R configuration.

 

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