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Q13.5(ii):
The Q value of a nuclear reaction \(A + b \rightarrow C + d\) is defined by \(Q = [ m_{A} + m_{b} – m_{C} – m_{d} ]c^{2}\) where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic. (ii) \(^{12}_{6}C+ ^{12}_{6}C \rightarrow ^{20}_{10}Ne+ ^{4}_{2}He\) Atomic masses are given to be \(m (\(^{2}_{1}H\)) = 2.014102 u\) \(m (\(^{3}_{1}H\)) = 3.016049 u\) \(m (\(^{12}_{6}C\)) = 12.000000 u\) \(m (\(^{20}_{10}Ne\)) = 19.992439 u\)

Solution :

Step 1: Identifying Reactant and Product Masses

The nuclear reaction is given as: $^{12}_{6}C + ^{12}_{6}C \rightarrow ^{20}_{10}Ne + ^{4}_{2}He$.

From the problem statement and standard physical constants, we identify the following atomic masses:

  • Mass of Reactant 1 ($m_A$): $m(^{12}_{6}C) = 12.000000 \, u$
  • Mass of Reactant 2 ($m_b$): $m(^{12}_{6}C) = 12.000000 \, u$
  • Mass of Product 1 ($m_C$): $m(^{20}_{10}Ne) = 19.992439 \, u$
  • Mass of Product 2 ($m_d$): $m(^{4}_{2}He) = 4.002603 \, u$ (standard value for Alpha particle)

Step 2: Calculating Mass Defect ($\Delta m$)

The mass defect is calculated by finding the difference between the total mass of the reactants and the total mass of the products [Per the definition of binding energy and mass-energy equivalence]:

$\Delta m = [ (m_A + m_b) - (m_C + m_d) ]$

$\Delta m = [ (12.000000 + 12.000000) - (19.992439 + 4.002603) ] \, u$

$\Delta m = [ 24.000000 - 23.995042 ] \, u$

$\Delta m = 0.004958 \, u$

Step 3: Calculating Q-value via Energy Equivalence

The Q-value is given by $Q = \Delta m \times c^{2}$. Given that $1 \, u \approx 931.5 \, MeV/c^{2}$ [By Einstein's Mass-Energy Equivalence Principle]:

$Q = 0.004958 \, u \times 931.5 \, MeV/u$

$Q \approx 4.6183 \, MeV$

Step 4: Classification of Reaction

The reaction type is determined by the sign of the Q-value:

Condition Classification
$Q > 0$ Exothermic (Energy released)
$Q < 0$ Endothermic (Energy absorbed)

Since the calculated $Q = +4.6183 \, MeV$, which is greater than zero, the reaction releases energy to the surroundings.

Reaction Progress Reactants (24.000000 u) Products (23.995042 u) Q = +4.6183 MeV (Released)

Final Solution: The Q-value is $4.6183 \, MeV$. Since $Q > 0$, the reaction is exothermic.


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