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Q11.9:
Light of wavelength 488 nm is produced by an argon laser which is used in the photoelectric effect. When light from this spectral line is incident on the emitter, the stopping (cut-off) potential of photoelectrons is 0.38 V. Find the work function of the material from which the emitter is made.

Solution :

Given Variables & Initial Setup

The photoelectric effect is governed by Einstein's Photoelectric Equation. We identify the provided physical constants and parameters:

  • Wavelength of incident light ($\lambda$): $488 \text{ nm} = 488 \times 10^{-9} \text{ m}$
  • Stopping potential ($V_0$): $0.38 \text{ V}$
  • Planck’s constant ($h$): $6.626 \times 10^{-34} \text{ J}\cdot\text{s}$
  • Speed of light ($c$): $3 \times 10^8 \text{ m/s}$
  • Elementary charge ($e$): $1.602 \times 10^{-19} \text{ C}$

Step 1: Calculate Energy of Incident Photon

The energy of an incident photon ($E$) is determined by the relation [Per the Planck-Einstein Relation]:

$E = \frac{hc}{\lambda}$

$E = \frac{(6.626 \times 10^{-34} \text{ J}\cdot\text{s}) \times (3 \times 10^8 \text{ m/s})}{488 \times 10^{-9} \text{ m}}$

$E \approx 4.073 \times 10^{-19} \text{ J}$

To convert Joules to electron-volts (eV) [Conversion factor: $1 \text{ eV} = 1.602 \times 10^{-19} \text{ J}$]:

$E (\text{in eV}) = \frac{4.073 \times 10^{-19}}{1.602 \times 10^{-19}} \approx 2.54 \text{ eV}$

Step 2: Calculate Maximum Kinetic Energy

The maximum kinetic energy ($K_{max}$) of the photoelectrons is related to the stopping potential ($V_0$) by the relation [Per the definition of Stopping Potential]:

$K_{max} = eV_0$

$K_{max} = e \times 0.38 \text{ V} = 0.38 \text{ eV}$

Step 3: Determining the Work Function

Einstein’s Photoelectric Equation states that the energy of the incident photon is the sum of the work function ($\Phi_0$) and the maximum kinetic energy [Per the Conservation of Energy]:

$E = \Phi_0 + K_{max}$

Rearranging for the work function:

$\Phi_0 = E - K_{max}$

$\Phi_0 = 2.54 \text{ eV} - 0.38 \text{ eV}$

$\Phi_0 = 2.16 \text{ eV}$

Visual Representation of Photoelectric Effect

Incident Photon (hν) Photoelectron (Kmax) Metal Surface (Work Function Φ0)

Final Solution: The work function of the material is 2.16 eV.


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