✕
Find the best tutors and institutes for Class 12 Tuition
Find Best Class 12 Tuition
Amines Exercises Solutions
- Q9.1 (i): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (i) \((CH_{3})_{2}CHNH_{2}\)
- Q9.1 (ii): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (ii) \(CH_{3}(CH_{2})_{2}NH_{2}\)
- Q9.1 (iii): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (iii) \(CH_{3}NHCH(CH_{3})_{2}\)
- Q9.1 (iv): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (iv) \((CH_{3})_{3}CNH_{2}\)
- Q9.1 (v): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (v) \(C_{6}H_{5}NHCH_{3}\)
- Q9.1 (vi): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (vi) \((CH_{3}CH_{2})_{2}NCH_{3}\)
- Q9.1 (vii): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (vii) \(m–BrC_{6}H_{4}NH_{2}\)
- Q9.1(i): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (i) (( (CH_{3})_{2}CHNH_{2} ))
- Q9.1(ii): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (ii) (( CH_{3}(CH_{2})_{2}NH_{2} ))
- Q9.1(iii): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (iii) (( CH_{3}NHCH(CH_{3})_{2} ))
- Q9.1(iv): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (iv) (( (CH_{3})_{3}CNH_{2} ))
- Q9.1(v): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (v) (( C_{6}H_{5}NHCH_{3} ))
- Q9.1(vi): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (vi) (( (CH_{3}CH_{2})_{2}NCH_{3} ))
- Q9.1(vii): Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines. (vii) (( m–BrC_{6}H_{4}NH_{2} ))
- Q9.10: An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound ‘B’ which on heating with \(Br_{2}\) and \(KOH\) forms a compound ‘C’ of molecular formula \(C_{6}H_{7}N\). Write the structures and IUPAC names of compounds A, B and C.
- Q9.10: An aromatic compound ‘A’ on treatment with aqueous ammonia and heating forms compound ‘B’ which on heating with (( Br_{2} )) and KOH forms a compound ‘C’ of molecular formula (( C_{6}H_{7}N )). Write the structures and IUPAC names of compounds A, B and C.
- Q9.11: Complete the following reactions:
- Q9.11 (i): Complete the following reactions: (i) \(C_{6}H_{5}NH_{2} + CHCl_{3} + \text{alc.}KOH \rightarrow\)
- Q9.11 (ii): Complete the following reactions: (ii) \(C_{6}H_{5}N_{2}^{+}Cl^{-} + H_{3}PO_{2} + H_{2}O \rightarrow\)
- Q9.11 (iii): Complete the following reactions: (iii) \(C_{6}H_{5}NH_{2} + H_{2}SO_{4} (\text{conc.}) \rightarrow\)
- Q9.11 (iv): Complete the following reactions: (iv) \(C_{6}H_{5}N_{2}^{+}Cl^{-} + C_{2}H_{5}OH \rightarrow\)
- Q9.11 (v): Complete the following reactions: (v) \(C_{6}H_{5}NH_{2} + Br_{2} (aq) \rightarrow\)
- Q9.11 (vi): Complete the following reactions: (vi) \(C_{6}H_{5}NH_{2} + (CH_{3}CO)_{2}O \rightarrow\)
- Q9.11(i): Complete the following reactions: (i) (( C_{6}H_{5}NH_{2} + CHCl_{3} + \text{alc.KOH} \rightarrow ))
- Q9.11(ii): Complete the following reactions: (ii) (( C_{6}H_{5}N_{2}^{+}Cl^{-} + H_{3}PO_{2} + H_{2}O \rightarrow ))
- Q9.11(iii): Complete the following reactions: (iii) (( C_{6}H_{5}NH_{2} + H_{2}SO_{4}(\text{conc.}) \rightarrow ))
- Q9.11(iv): Complete the following reactions: (iv) (( C_{6}H_{5}N_{2}^{+}Cl^{-} + C_{2}H_{5}OH \rightarrow ))
- Q9.11(v): Complete the following reactions: (v) (( C_{6}H_{5}NH_{2} + Br_{2}(aq) \rightarrow ))
- Q9.11(vi): Complete the following reactions: (vi) (( C_{6}H_{5}NH_{2} + (CH_{3}CO)_{2}O \rightarrow ))
- Q9.11(vii): Complete the following reactions: (vii) (( C_{6}H_{5}N_{2}^{+}Cl^{-} \xrightarrow{(i)HBF_{4} (ii)NaNO_{2}/Cu, \Delta} ))
- Q9.12: Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
- Q9.12: Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
- Q9.13 (i): Write the reactions of (i) aromatic primary amines with nitrous acid.
- Q9.13 (ii): Write the reactions of (ii) aliphatic primary amines with nitrous acid.
- Q9.13(i): Write the reactions of aromatic primary amines with nitrous acid.
- Q9.13(ii): Write the reactions of aliphatic primary amines with nitrous acid.
- Q9.14 (i): Give plausible explanation for each of the following: (i) Why are amines less acidic than alcohols of comparable molecular masses?
- Q9.14 (ii): Give plausible explanation for each of the following: (ii) Why do primary amines have higher boiling point than tertiary amines?
- Q9.14 (iii): Give plausible explanation for each of the following: (iii) Why are aliphatic amines stronger bases than aromatic amines?
- Q9.14(i): Give plausible explanation for each of the following: (i) Why are amines less acidic than alcohols of comparable molecular masses?
- Q9.14(ii): Give plausible explanation for each of the following: (ii) Why do primary amines have higher boiling point than tertiary amines?
- Q9.14(iii): Give plausible explanation for each of the following: (iii) Why are aliphatic amines stronger bases than aromatic amines?
- Q9.2 (i): Give one chemical test to distinguish between the following pairs of compounds. (i) Methylamine and dimethylamine
- Q9.2 (ii): Give one chemical test to distinguish between the following pairs of compounds. (ii) Secondary and tertiary amines
- Q9.2 (iii): Give one chemical test to distinguish between the following pairs of compounds. (iii) Ethylamine and aniline
- Q9.2 (iv): Give one chemical test to distinguish between the following pairs of compounds. (iv) Aniline and benzylamine
- Q9.2 (v): Give one chemical test to distinguish between the following pairs of compounds. (v) Aniline and N-methylaniline.
- Q9.2(i): Give one chemical test to distinguish between the following pairs of compounds. (i) Methylamine and dimethylamine
- Q9.2(ii): Give one chemical test to distinguish between the following pairs of compounds. (ii) Secondary and tertiary amines
- Q9.2(iii): Give one chemical test to distinguish between the following pairs of compounds. (iii) Ethylamine and aniline
- Q9.2(iv): Give one chemical test to distinguish between the following pairs of compounds. (iv) Aniline and benzylamine
- Q9.2(v): Give one chemical test to distinguish between the following pairs of compounds. (v) Aniline and N-methylaniline.
- Q9.3 (i): Account for the following: (i) \(pK_{b}\) of aniline is more than that of methylamine.
- Q9.3 (ii): Account for the following: (ii) Ethylamine is soluble in water whereas aniline is not.
- Q9.3 (iii): Account for the following: (iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
- Q9.3 (iv): Account for the following: (iv) Although amino group is \(o–\) and \(p–\) directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of \(m\)-nitroaniline.
- Q9.3 (v): Account for the following: (v) Aniline does not undergo Friedel-Crafts reaction.
- Q9.3 (vi): Account for the following: (vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines.
- Q9.3 (vii): Account for the following: (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
- Q9.3(i): Account for the following: (i) (( pK_{b} )) of aniline is more than that of methylamine.
- Q9.3(ii): Account for the following: (ii) Ethylamine is soluble in water whereas aniline is not.
- Q9.3(iii): Account for the following: (iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.
- Q9.3(iv): Account for the following: (iv) Although amino group is (( o– )) and (( p– )) directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of (( m ))-nitroaniline.
- Q9.3(v): Account for the following: (v) Aniline does not undergo Friedel-Crafts reaction.
- Q9.3(vi): Account for the following: (vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines.
- Q9.3(vii): Account for the following: (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.
- Q9.4 (i): Arrange the following: (i) In decreasing order of the \(pK_{b}\) values: \(C_{2}H_{5}NH_{2}\), \(C_{6}H_{5}NHCH_{3}\), \((C_{2}H_{5})_{2}NH\) and \(C_{6}H_{5}NH_{2}\)
- Q9.4 (ii): Arrange the following: (ii) In increasing order of basic strength: \(C_{6}H_{5}NH_{2}\), \(C_{6}H_{5}N(CH_{3})_{2}\), \((C_{2}H_{5})_{2}NH\) and \(CH_{3}NH_{2}\)
- Q9.4 (iii)(a): Arrange the following: (iii) In increasing order of basic strength: (a) Aniline, \(p\)-nitroaniline and \(p\)-toluidine
- Q9.4 (iii)(b): Arrange the following: (iii) In increasing order of basic strength: (b) \(C_{6}H_{5}NH_{2}\), \(C_{6}H_{5}NHCH_{3}\), \(C_{6}H_{5}CH_{2}NH_{2}\).
- Q9.4 (iv): Arrange the following: (iv) In decreasing order of basic strength in gas phase: \(C_{2}H_{5}NH_{2}\), \((C_{2}H_{5})_{2}NH\), \((C_{2}H_{5})_{3}N\) and \(NH_{3}\)
- Q9.4 (v): Arrange the following: (v) In increasing order of boiling point: \(C_{2}H_{5}OH\), \((CH_{3})_{2}NH\), \(C_{2}H_{5}NH_{2}\)
- Q9.4 (vi): Arrange the following: (vi) In increasing order of solubility in water: \(C_{6}H_{5}NH_{2}\), \((C_{2}H_{5})_{2}NH\), \(C_{2}H_{5}NH_{2}\).
- Q9.4(i): Arrange the following: (i) In decreasing order of the (( pK_{b} )) values: (( C_{2}H_{5}NH_{2} )), (( C_{6}H_{5}NHCH_{3} )), (( (C_{2}H_{5})_{2}NH )) and (( C_{6}H_{5}NH_{2} ))
- Q9.4(ii): Arrange the following: (ii) In increasing order of basic strength: (( C_{6}H_{5}NH_{2} )), (( C_{6}H_{5}N(CH_{3})_{2} )), (( (C_{2}H_{5})_{2}NH )) and (( CH_{3}NH_{2} ))
- Q9.4(iii)(a): Arrange the following: (iii) In increasing order of basic strength: (a) Aniline, (( p ))-nitroaniline and (( p ))-toluidine
- Q9.4(iii)(b): Arrange the following: (iii) In increasing order of basic strength: (b) (( C_{6}H_{5}NH_{2} )), (( C_{6}H_{5}NHCH_{3} )), (( C_{6}H_{5}CH_{2}NH_{2} )).
- Q9.4(iv): Arrange the following: (iv) In decreasing order of basic strength in gas phase: (( C_{2}H_{5}NH_{2} )), (( (C_{2}H_{5})_{2}NH )), (( (C_{2}H_{5})_{3}N )) and (( NH_{3} ))
- Q9.4(v): Arrange the following: (v) In increasing order of boiling point: (( C_{2}H_{5}OH )), (( (CH_{3})_{2}NH )), (( C_{2}H_{5}NH_{2} ))
- Q9.4(vi): Arrange the following: (vi) In increasing order of solubility in water: (( C_{6}H_{5}NH_{2} )), (( (C_{2}H_{5})_{2}NH )), (( C_{2}H_{5}NH_{2} )).
- Q9.5 (i): How will you convert: (i) Ethanoic acid into methanamine
- Q9.5 (ii): How will you convert: (ii) Hexanenitrile into 1-aminopentane
- Q9.5 (iii): How will you convert: (iii) Methanol to ethanoic acid
- Q9.5 (iv): How will you convert: (iv) Ethanamine into methanamine
- Q9.5 (v): How will you convert: (v) Ethanoic acid into propanoic acid
- Q9.5 (vi): How will you convert: (vi) Methanamine into ethanamine
- Q9.5 (vii): How will you convert: (vii) Nitromethane into dimethylamine
- Q9.5 (viii): How will you convert: (viii) Propanoic acid into ethanoic acid?
- Q9.5(i): How will you convert: (i) Ethanoic acid into methanamine
- Q9.5(ii): How will you convert: (ii) Hexanenitrile into 1-aminopentane
- Q9.5(iii): How will you convert: (iii) Methanol to ethanoic acid
- Q9.5(iv): How will you convert: (iv) Ethanamine into methanamine
- Q9.5(v): How will you convert: (v) Ethanoic acid into propanoic acid
- Q9.5(vi): How will you convert: (vi) Methanamine into ethanamine
- Q9.5(vii): How will you convert: (vii) Nitromethane into dimethylamine
- Q9.5(viii): How will you convert: (viii) Propanoic acid into ethanoic acid?
- Q9.6: Describe a method for the identification of primary, secondary and tertiary amines. Also write chemical equations of the reactions involved.
- Q9.6: Describe a method for the identification of primary, secondary and tertiary amines. Also write chemical equations of the reactions involved.
- Q9.7 (i): Write short notes on the following: (i) Carbylamine reaction
- Q9.7 (ii): Write short notes on the following: (ii) Diazotisation
- Q9.7 (iii): Write short notes on the following: (iii) Hofmann’s bromamide reaction
- Q9.7 (iv): Write short notes on the following: (iv) Coupling reaction
- Q9.7 (v): Write short notes on the following: (v) Ammonolysis
- Q9.7 (vi): Write short notes on the following: (vi) Acetylation
- Q9.7 (vii): Write short notes on the following: (vii) Gabriel phthalimide synthesis.
- Q9.7(i): Write short notes on the following: (i) Carbylamine reaction
- Q9.7(ii): Write short notes on the following: (ii) Diazotisation
- Q9.7(iii): Write short notes on the following: (iii) Hofmann’s bromamide reaction
- Q9.7(iv): Write short notes on the following: (iv) Coupling reaction
- Q9.7(v): Write short notes on the following: (v) Ammonolysis
- Q9.7(vi): Write short notes on the following: (vi) Acetylation
- Q9.7(vii): Write short notes on the following: (vii) Gabriel phthalimide synthesis.
- Q9.8 (i): Accomplish the following conversions: (i) Nitrobenzene to benzoic acid
- Q9.8 (ii): Accomplish the following conversions: (ii) Benzene to \(m\)-bromophenol
- Q9.8 (iii): Accomplish the following conversions: (iii) Benzoic acid to aniline
- Q9.8 (iv): Accomplish the following conversions: (iv) Aniline to 2,4,6-tribromofluorobenzene
- Q9.8 (ix): Accomplish the following conversions: (ix) Aniline to benzyl alcohol.
- Q9.8 (v): Accomplish the following conversions: (v) Benzyl chloride to 2-phenylethanamine
- Q9.8 (vi): Accomplish the following conversions: (vi) Chlorobenzene to \(p\)-chloroaniline
- Q9.8 (vii): Accomplish the following conversions: (vii) Aniline to \(p\)-bromoaniline
- Q9.8 (viii): Accomplish the following conversions: (viii) Benzamide to toluene
- Q9.8(i): Accomplish the following conversions: (i) Nitrobenzene to benzoic acid
- Q9.8(ii): Accomplish the following conversions: (ii) Benzene to m-bromophenol
- Q9.8(iii): Accomplish the following conversions: (iii) Benzoic acid to aniline
- Q9.8(iv): Accomplish the following conversions: (iv) Aniline to 2,4,6-tribromofluorobenzene
- Q9.8(ix): Accomplish the following conversions: (ix) Aniline to benzyl alcohol.
- Q9.8(v): Accomplish the following conversions: (v) Benzyl chloride to 2-phenylethanamine
- Q9.8(vi): Accomplish the following conversions: (vi) Chlorobenzene to p-chloroaniline
- Q9.8(vii): Accomplish the following conversions: (vii) Aniline to p-bromoaniline
- Q9.8(viii): Accomplish the following conversions: (viii) Benzamide to toluene
- Q9.9: Give the structures of A, B and C in the following reactions:
- Q9.9: Give the structures of A, B and C in the following reactions:
- Q9.9: Give the structures of A, B and C in the following reactions:
- Q9.9: Give the structures of A, B and C in the following reactions:
- Q9.9: Give the structures of A, B and C in the following reactions:
- Q9.9: Give the structures of A, B and C in the following reactions:
- Q9.9(i): Give the structures of A, B and C in the following reactions: (i) (( CH_{3}CH_{2}I \xrightarrow{NaCN} A \xrightarrow{OH^{-}/ \text{Partial hydrolysis}} B \xrightarrow{NaOH + Br_{2}} C ))
- Q9.9(ii): Give the structures of A, B and C in the following reactions: (ii) (( C_{6}H_{5}N_{2}^{+}Cl^{-} \xrightarrow{CuCN} A \xrightarrow{H_{2}O/H^{+}} B \xrightarrow{NH_{3}, \Delta} C ))
- Q9.9(iii): Give the structures of A, B and C in the following reactions: (iii) (( CH_{3}CH_{2}Br \xrightarrow{KCN} A \xrightarrow{LiAlH_{4}} B \xrightarrow{HNO_{2}, 0^{\circ}C} C ))
- Q9.9(iv): Give the structures of A, B and C in the following reactions: (iv) (( C_{6}H_{5}NO_{2} \xrightarrow{Fe/HCl} A \xrightarrow{NaNO_{2} + HCl, 273 K} B \xrightarrow{H_{2}O/H^{+}, \Delta} C ))
- Q9.9(v): Give the structures of A, B and C in the following reactions: (v) (( CH_{3}COOH \xrightarrow{NH_{3}, \Delta} A \xrightarrow{NaOBr} B \xrightarrow{NaNO_{2}/HCl} C ))
- Q9.9(vi): Give the structures of A, B and C in the following reactions: (vi) (( C_{6}H_{5}NO_{2} \xrightarrow{Fe/HCl} A \xrightarrow{HNO_{2}, 273K} B \xrightarrow{C_{6}H_{5}OH} C ))
Chapters in CBSE - Class 12 Chemistry
Top Tutors who teach Amines
(14)
Top Tutor
Noida Industrial Area, Noida
10 yrs of
Exp
5 students
98 hrs of classes completed
400
per hour
Mathematics Teacher with more then 12 years Experience to teach maths
Online Classes
Student's Home
Tutor's home
I have both experience and knowledge in tutoring of Mathematics. I have been giving tutoring for last 10 years. I have a great academic record both at school and college level. I believe in making the student understand the concept which is important from exam point of view also and also for future growth of student Personal attention with quality learning can provide you better understanding of concepts. This is what I want to ensure to the students so that I will be able to make difference between their past, present and future. I am also a good motivator and a creative person as well. So, it will help the students to learn the concepts clearly. I find satisfaction in making students understand their subjects by making them finding their own areas of strength. As I qualified GATE and have a good exposure of lab so I know the level of topics and questions ask in competitive exams. I am motivated person so always try to appreciate and boost my students. Good in communications. My focus will be on developing a strong base of each and every subject taught to the student. Innovative techniques of learning will be introduced based on the efficiency of the student to grasp the subject matter. Another area of focus would be helping the students to strategies methodology for self-study purpose. Adequate time will be provided and clearing doubts will always be the top priority. Fluency in all subjects is assured.
Skills:
Mathematics
Also teaches:
BTech Tuition, UPSC Exams Coaching
and more
(39)
Top Tutor
Siraspur, Delhi
9 yrs of
Exp
21 students
1446 hrs of classes completed
500
per hour
Commerce lecturer with 11 years experience in teaching.I am working in Delhi govt school
Online Classes
Tutor's home
I am well aware how to use keywords to solve questions in mcq's and case study. I have good knowledge and presentation of my subject. Students can take mock test and get pdf for exam sample paper.
Annu Shaw
Seema Ma’am has been teaching me Accounts since Grade 11, and now I’m continuing Grade 12 with her as well. Her explanation style is absolutely flawless and extremely easy to understand. She teaches every concept from the basic level, which makes even difficult topics feel simple and clear. She tells keywords and also gives tricks and hacks which will tackle the twists mcqs and questions...also she made me practice a lot through worksheets and sample papers which helped me to complete my paper on time. I am very confident with my accounts subject because of her guidance and teaching-style.
Skills:
Economics
,
Accountancy
and more
Also teaches:
CUET Coaching, Class 11 Tuition
(5)
Top Tutor
Chopasni Housing Board, Jodhpur
3 yrs of
Exp
LEARN WITH ME AND FEEL THE DIFFERENCE IN YOUR MARKS
Student's Home
Tutor's home
i have taught to various students and commerce is my main stream. i am persuing CA course and i am interested in accounting, economics and business studies subjects. i am interested in teaching to school and college students.
Skills:
Economics
,
Accountancy
and more
Also teaches:
Class 9 Tuition, Class I-V Tuition
and more
(36)
Top Tutor
Bhagalpur, Bhagalpur
15 yrs of
Exp
3 students
121 hrs of classes completed
600
per hour
Break The Term, Learn The Biology
Online Classes
Biology like never before, every line of NCERT elaborating with a lot of mnemonics to make learning so easy
Gabriella Sawkmie mawlong
I strongly recommend sir. His dedication to his students is unmatched, consistently going above and beyond to ensure they understand and excel in their studies. He takes the time to personalize his approach for each student, recognizing their unique strengths and areas for improvement. He has an unwavering commitment to motivating his students. He knows how to inspire confidence, push them to reach their full potential, and ignite a genuine passion for learning.
Skills:
Biology
Also teaches:
Class 11 Tuition, NEET-UG Coaching
(27)
Top Tutor
Biman Nagar, Kolkata
8 yrs of
Exp
500
per hour
Physics Tutor for NEET and JEE
Online Classes
Student's Home
Tutor's home
I am actively teaching physics up to class XII ( including JEE and NEET aspirants) from last 8 years. I run my own Tuition center where I provide physics class to NEET and IIT JEE aspirants and provide home Tuitions to deserving students. There is a separate doubt clearance & numerical problem solving batch for candidate who already joined Aakash, fiit jee, Allen and other coaching institutes.
Skills:
Physics
Also teaches:
Class 11 Tuition, Engineering Entrance Coaching
and more
×
