4.
Calculate the enthalpy change for the process
$CCl_4(g) \rightarrow C(g) + 4 Cl(g)$
and calculate bond enthalpy of C – Cl in $CCl_4(g)$.
$Δ_{vap}H^o(CCl_4) = 30.5 \text{ kJ mol}^{-1}$.
$Δ_fH^o (CCl_4) = -135.5 \text{ kJ mol}^{-1}$.
$Δ_aH^o (C) = 715.0 \text{ kJ mol}^{-1}$, where $Δ_aH^o$ is enthalpy of atomisation
$Δ_aH^o (Cl_2) = 242 \text{ kJ mol}^{-1}$