UrbanPro

Your Worksheet is Ready

CBSE - Class 11 Chemistry Thermodynamics Worksheet

EXERCISES

1.
Enthalpy of combustion of carbon to $CO_2$ is $-393.5 \text{ kJ mol}^{-1}$. Calculate the heat released upon formation of 35.2 g of $CO_2$ from carbon and dioxygen gas.
2.
Enthalpies of formation of $CO(g)$, $CO_2(g)$, $N_2O(g)$ and $N_2O_4(g)$ are $-110$, $-393$, 81 and $9.7 \text{ kJ mol}^{-1}$ respectively. Find the value of $Δ_rH$ for the reaction:
$N_2O_4(g) + 3CO(g) \rightarrow N_2O(g) + 3CO_2(g)$
3.
Comment on the thermodynamic stability of $NO(g)$, given
$\frac{1}{2} N_2(g) + \frac{1}{2}O_2(g) \rightarrow NO(g)$; $Δ_rH^o = 90 \text{ kJ mol}^{-1}$
$NO(g) + \frac{1}{2}O_2(g) \rightarrow NO_2(g)$: $Δ_rH^o= -74 \text{ kJ mol}^{-1}$
4.
The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, $-890.3 \text{ kJ mol}^{-1}$, $-393.5 \text{ kJ mol}^{-1}$, and $-285.8 \text{ kJ mol}^{-1}$ respectively. Enthalpy of formation of $CH_4(g)$ will be
a. $-74.8 \text{ kJ mol}^{-1}$ b. $-52.27 \text{ kJ mol}^{-1}$ c. $+74.8 \text{ kJ mol}^{-1}$ d. $+52.26 \text{ kJ mol}^{-1}$
5.
For the reaction at 298 K,
$2A + B \rightarrow C$
$ΔH = 400 \text{ kJ mol}^{-1}$ and $ΔS = 0.2 \text{ kJ K}^{-1} \text{ mol}^{-1}$
At what temperature will the reaction become spontaneous considering $ΔH$ and $ΔS$ to be constant over the temperature range.
6.
A reaction, $A + B \rightarrow C + D + q$ is found to have a positive entropy change. The reaction will be
a. possible at high temperature b. possible only at low temperature c. not possible at any temperature d. possible at any temperature
7.
For the reaction,
$2 Cl(g) \rightarrow Cl_2(g)$, what are the signs of $ΔH$ and $ΔS$ ?
8.
The reaction of cyanamide, $NH_2CN (s)$, with dioxygen was carried out in a bomb calorimeter, and $ΔU$ was found to be $-742.7 \text{ kJ mol}^{-1}$ at 298 K. Calculate enthalpy change for the reaction at 298 K.
$NH_2CN(g) + \frac{3}{2}O_2(g) \rightarrow N_2(g) + CO_2(g) + H_2O(l)$
9.
In a process, 701 J of heat is absorbed by a system and 394 J of work is done by the system. What is the change in internal energy for the process?
10.
For the reaction
$2 A(g) + B(g) \rightarrow 2D(g)$
$ΔU^o = -10.5 \text{ kJ}$ and $ΔS^o = -44.1 \text{ JK}^{-1}$.
Calculate $ΔG^o$ for the reaction, and predict whether the reaction may occur spontaneously.
11.
The equilibrium constant for a reaction is 10. What will be the value of $ΔG^o$ ? $R = 8.314 \text{ JK}^{-1} \text{ mol}^{-1}$, $T = 300 K$.
12.
For the process to occur under adiabatic conditions, the correct condition is:
a. $?T = 0$ b. $?p = 0$ c. $q = 0$ d. $w = 0$
13.
Choose the correct answer. A thermodynamic state function is a quantity
a. used to determine heat changes b. whose value is independent of path c. used to determine pressure volume work d. whose value depends on temperature only.
14.
Given
$N_2(g) + 3H_2(g) \rightarrow 2NH_3(g)$; $Δ_rH^o = -92.4 \text{ kJ mol}^{-1}$
What is the standard enthalpy of formation of $NH_3$ gas?
15.
The enthalpies of all elements in their standard states are:
a. unity b. zero c. < 0 d. different for each element
16.
Calculate the standard enthalpy of formation of $CH_3OH(l)$ from the following data:
$CH_3OH (l) + \frac{3}{2} O_2(g) \rightarrow CO_2(g) + 2H_2O(l)$ ; $Δ_rH^o = -726 \text{ kJ mol}^{-1}$
$C(graphite) + O_2(g) \rightarrow CO_2(g)$ ; $Δ_cH^o = -393 \text{ kJ mol}^{-1}$
$H_2(g) + \frac{1}{2} O_2(g) \rightarrow H_2O(l)$; $Δ_fH^o = -286 \text{ kJ mol}^{-1}$.
17.
Calculate the entropy change in surroundings when 1.00 mol of $H_2O(l)$ is formed under standard conditions. $Δ_fH^o = -286 \text{ kJ mol}^{-1}$.
18.
Calculate the enthalpy change for the process
$CCl_4(g) \rightarrow C(g) + 4 Cl(g)$
and calculate bond enthalpy of C – Cl in $CCl_4(g)$.
$Δ_{vap}H^o(CCl_4) = 30.5 \text{ kJ mol}^{-1}$.
$Δ_fH^o (CCl_4) = -135.5 \text{ kJ mol}^{-1}$.
$Δ_aH^o (C) = 715.0 \text{ kJ mol}^{-1}$, where $Δ_aH^o$ is enthalpy of atomisation
$Δ_aH^o (Cl_2) = 242 \text{ kJ mol}^{-1}$
19.
$ΔU^o$ of combustion of methane is $-X \text{ kJ mol}^{-1}$. The value of $ΔH^o$ is
a. $= ?U^o$ b. > $?U^o$ c. < $?U^o$ d. $= 0$
20.
For an isolated system, $ΔU = 0$, what will be $ΔS$ ?

Worksheet Answers

4.
6.
12.
13.
15.
19.

This website uses cookies

We use cookies to improve user experience. Choose what cookies you allow us to use. You can read more about our Cookie Policy in our Privacy Policy

Accept All
Decline All