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CBSE - Class 11 Chemistry Some Basic Concepts of Chemistry Worksheet
EXERCISES
Worksheet Answers
Solution:
To calculate the molar mass of Methane ($CH_4$), we must sum the atomic masses of the constituent elements, weighted by their respective number of atoms per molecule, as defined by the law of conservation of mass in molecular structures [Per Dalton’s Atomic Theory].
The molar mass ($M$) of a compound is defined as the summation of the products of the number of atoms and their respective atomic masses [By definition of Molar Mass/Formula Mass]:
$M(CH_4) = (n_C \times A_C) + (n_H \times A_H)$
Substituting the values into the formula:
$M(CH_4) = (1 \times 12.011 \, \text{g/mol}) + (4 \times 1.008 \, \text{g/mol})$
$M(CH_4) = 12.011 \, \text{g/mol} + 4.032 \, \text{g/mol}$
Summing the components to reach the final molar mass:
$M(CH_4) = 16.043 \, \text{g/mol}$
Final Solution: The molar mass of $CH_4$ is $16.043 \, \text{g/mol}$.
Solution:
The given quantity is $28.7\text{ pm}$. Here, "$\text{pm}$" represents the prefix "pico" appended to the base unit "meter" ($m$). The base unit of length in the International System of Units (SI) is the meter ($m$). [Per the SI brochure defined by the Bureau International des Poids et Mesures (BIPM)].
The prefix "pico" ($\text{p}$) is a standard sub-multiple factor used to express extremely small lengths. According to the SI system of prefixes:
Therefore, the conversion factor is:
$1\text{ pm} = 10^{-12}\text{ m}$ [By definition of SI prefixes]
To convert the given value into the base unit, we multiply the magnitude by the conversion factor:
$28.7\text{ pm} = 28.7 \times (10^{-12}\text{ m})$
To express the result in standard scientific notation ($a \times 10^n$, where $1 \le a < 10$):
$28.7 = 2.87 \times 10^1$
Substituting this back into the expression:
$28.7 \times 10^{-12}\text{ m} = (2.87 \times 10^1) \times 10^{-12}\text{ m}$
Applying the rule of exponents ($a^m \times a^n = a^{m+n}$):
$2.87 \times 10^{(1 - 12)}\text{ m} = 2.87 \times 10^{-11}\text{ m}$
Final Solution: $2.87 \times 10^{-11}\text{ m}$
Solution:
To calculate the distance, we must ensure all physical quantities are in base SI units (meters and seconds). The given parameters are:
Applying the unit conversion for nanoseconds ($1 \, ns = 10^{-9} \, s$):
$t = 2.00 \times 10^{-9} \, s$ [Definition of the SI prefix 'nano']
Since the speed of light in a vacuum is constant, we utilize the fundamental kinematic relationship for uniform motion:
$d = v \times t$ [Per the definition of velocity: $v = \frac{\Delta x}{\Delta t}$]
Substituting the values into the governing equation:
$d = (3.0 \times 10^8 \, m \, s^{-1}) \times (2.00 \times 10^{-9} \, s)$
Perform multiplication of the coefficients and powers of 10 independently:
$d = (3.0 \times 2.00) \times (10^8 \times 10^{-9}) \, m$
$d = 6.0 \times 10^{-1} \, m$
$d = 0.60 \, m$
In the multiplication $(3.0 \times 10^8) \times (2.00 \times 10^{-9})$:
Our result $0.60 \, m$ correctly maintains 2 significant figures.
Final Solution: The distance covered by light in 2.00 ns is 0.60 m.
Solution:
To determine the number of significant figures in the result of multiplication and division, the rule is to round the final answer to the same number of significant figures as the number with the fewest significant figures in the calculation [Per the Rules for Significant Figures in Multiplication/Division].
| Value | Number of Significant Figures | Justification |
|---|---|---|
| $0.02856$ | 4 | Leading zeros are not significant; digits 2, 8, 5, 6 are significant. |
| $298.15$ | 5 | All non-zero digits and zeros between them are significant. |
| $0.112$ | 3 | Leading zeros are not significant; digits 1, 1, 2 are significant. |
| $0.5785$ | 4 | Leading zero is not significant; digits 5, 7, 8, 5 are significant. |
We compare the significant figures identified in Step 1:
The precision of the final product/quotient is limited by the least precise measurement. Since the least precise term ($0.112$) has 3 significant figures, the final result must be rounded to 3 significant figures to maintain scientific integrity [Per the Convention of Significant Figures].
Final Solution: The answer should be reported with 3 significant figures.
Solution:
The molecular formula of ethane is $C_2H_6$. This chemical representation indicates that one molecule of ethane contains $2$ atoms of carbon and $6$ atoms of hydrogen. Consequently, one mole of ethane ($C_2H_6$) contains $6$ moles of hydrogen atoms [Per the Law of Definite Proportions and Avogadro's Hypothesis].
To determine the total number of moles of hydrogen atoms present in the sample, we identify the following inputs:
The total number of moles of hydrogen atoms ($n_H$) is calculated by multiplying the total moles of the compound by the stoichiometric coefficient of the hydrogen atoms within one molecule of that compound [By Stoichiometric Stoichiometric Relationship]:
$n_H = n_{ethane} \times 6$
$n_H = 3 \, \text{mol} \times 6$
$n_H = 18 \, \text{mol}$
| Substance | Quantity (moles) | H-atoms per unit |
|---|---|---|
| Ethane ($C_2H_6$) | $3$ | $6$ |
| Hydrogen ($H$) | $18$ | $1$ |
Final Solution: 18 moles of hydrogen atoms.
Solution:
According to [Avogadro’s Law] and the [Ideal Gas Law], the molar volume of any ideal gas at Standard Temperature and Pressure (STP) is defined as $22.4 \text{ L/mol}$. The molar mass ($M$) of a gas can be derived from the density ($\rho$) or the mass ($m$) of a known volume ($V$) at STP using the following relationship:
$M = \frac{m}{V} \times V_m$
Where:
By substituting the given experimental values into the derived formula:
$M = \frac{11.6 \text{ g}}{10.0 \text{ L}} \times 22.4 \text{ L/mol}$
Performing the arithmetic operation:
$M = 1.16 \text{ g/L} \times 22.4 \text{ L/mol}$
$M = 25.984 \text{ g/mol}$
Following the rules of [Significant Figures], the input values $11.6$ and $10.0$ possess three significant figures. Consequently, the final result must be rounded to three significant figures.
$25.984 \approx 26.0 \text{ g/mol}$
Final Solution: The molar mass of the welding gas is 26.0 g/mol.
Solution:
The expression $0.50 \text{ mol } Na_2CO_3$ refers to a specific amount of substance measured in moles. This is an absolute quantity of matter, independent of the volume of solvent or the concentration of the resulting solution.
The expression $0.50 \text{ M } Na_2CO_3$ refers to the molarity (molar concentration) of a solution. This is an intensive property indicating the ratio of solute amount to the total volume of the solution.
| Attribute | $0.50 \text{ mol } Na_2CO_3$ | $0.50 \text{ M } Na_2CO_3$ |
|---|---|---|
| Category | Amount of substance | Concentration (Molarity) |
| Dimension | Amount ($n$) | Amount per unit volume ($n/V$) |
| SI Unit | $\text{mol}$ | $\text{mol/L}$ (or $\text{M}$) |
| Volume Dependence | Independent of volume | Dependent on total volume |
Final Solution: $0.50 \text{ mol } Na_2CO_3$ represents a fixed mass of $53.0 \text{ g}$ of the solute, whereas $0.50 \text{ M } Na_2CO_3$ defines a solution concentration where $0.50 \text{ moles}$ of the solute are dissolved in every $1 \text{ liter}$ of the final solution. The former is an absolute quantity, while the latter is a ratio describing density of particles per unit volume.
Solution:
The combustion reaction is: $C_xH_y + O_2 \rightarrow CO_2 + H_2O$. We utilize the law of conservation of mass to determine the mass of carbon and hydrogen contained within the initial fuel sample [Per the Law of Conservation of Mass].
Mass of Carbon in $CO_2$:
Molar mass of $CO_2 = 12.01 + (2 \times 16.00) = 44.01 \, \text{g/mol}$.
Mass of Carbon = $\left( \frac{12.01 \, \text{g/mol}}{44.01 \, \text{g/mol}} \right) \times 3.38 \, \text{g} = 0.9226 \, \text{g}$
Mass of Hydrogen in $H_2O$:
Molar mass of $H_2O = (2 \times 1.008) + 16.00 = 18.016 \, \text{g/mol}$.
Mass of Hydrogen = $\left( \frac{2 \times 1.008 \, \text{g/mol}}{18.016 \, \text{g/mol}} \right) \times 0.690 \, \text{g} = 0.0772 \, \text{g}$
Now, we convert the mass of each element into its respective moles to determine the atomic ratio.
| Element | Mass (g) | Atomic Mass (g/mol) | Moles ($n = \frac{m}{M}$) |
|---|---|---|---|
| Carbon | 0.9226 | 12.01 | $0.0768$ |
| Hydrogen | 0.0772 | 1.008 | $0.0766$ |
Divide each mole value by the smallest value ($0.0766$) to find the integer ratio [Per Dalton's Atomic Theory].
Since the ratio of $C:H$ is $1:1$, the empirical formula represents the simplest whole-number ratio of atoms in the compound.
Final Solution: The empirical formula of the welding fuel gas is $\text{CH}$.
Solution:
The balanced chemical equation for the reaction is:
$A + B_2 \rightarrow AB_2$
From the balanced equation, we observe the stoichiometric coefficients [Per Law of Conservation of Mass]:
We are provided with the following quantities:
The limiting reagent is the reactant that is entirely consumed in a reaction and determines the amount of product formed [By Definition of Limiting Reagent in Stoichiometry].
To identify the limiting reagent, we compare the available moles to the stoichiometric coefficients:
| Reactant | Available Quantity | Stoichiometric Ratio | Comparison |
|---|---|---|---|
| $A$ | $300$ | $1$ | $300/1 = 300$ |
| $B_2$ | $200$ | $1$ | $200/1 = 200$ |
Since the ratio for $B_2$ ($200$) is less than the ratio for $A$ ($300$), $B_2$ will be consumed first.
Because $200$ molecules of $B_2$ can only react with $200$ atoms of $A$, there will be $300 - 200 = 100$ atoms of $A$ remaining in excess.
Final Solution: The limiting reagent is $B_2$.
Solution:
Significant figures are defined as the meaningful digits in a measured or calculated quantity. They represent the precision of the measurement, including all certain digits plus the first uncertain digit [Per IUPAC Guidelines for Chemical Nomenclature and Data].
The number under consideration is $126,000$. According to the established rules of scientific measurement:
Without additional information or a decimal point at the end, the trailing zeros in $126,000$ are generally treated as non-significant placeholders indicating the magnitude of the value rather than the precision of the measurement. Thus, only the non-zero digits are counted.
Based on the standard protocol for whole numbers ending in zeros, the significant digits are $1, 2,$ and $6$. The three trailing zeros serve only to place the decimal point and are not significant.
Final Solution: The number 126,000 has 3 significant figures.
Solution:
To determine the molar concentration (molarity) of the sugar solution, we identify the following parameters provided in the problem statement:
Using the atomic masses of Carbon ($C = 12.01\text{ g/mol}$), Hydrogen ($H = 1.008\text{ g/mol}$), and Oxygen ($O = 16.00\text{ g/mol}$), we apply the sum rule for molecular mass [Per Dalton’s Atomic Theory and the Law of Definite Proportions]:
$M_m = (12 \times 12.01) + (22 \times 1.008) + (11 \times 16.00)$
$M_m = 144.12 + 22.176 + 176.00 = 342.296\text{ g/mol}$
Rounding to standard precision for textbook stoichiometry: $M_m \approx 342.3\text{ g/mol}$.
The number of moles ($n$) is calculated by dividing the given mass by the molar mass [Per the definition of the Mole concept]:
$n = \frac{m}{M_m}$
$n = \frac{20\text{ g}}{342.3\text{ g/mol}} \approx 0.05843\text{ mol}$
Molarity is defined as the number of moles of solute per liter of solution [Per the IUPAC definition of Molar Concentration]:
$M = \frac{n (\text{mol})}{V (\text{L})}$
$M = \frac{0.05843\text{ mol}}{2\text{ L}} = 0.029215\text{ mol L}^{-1}$
Final Solution: The concentration of the sugar solution is $0.0292\text{ mol L}^{-1}$.
Solution:
The provided equation is $N_2 (g) + H_2 (g) \rightarrow 2NH_3 (g)$. To satisfy the Law of Conservation of Mass [Per Dalton's Atomic Theory], the number of atoms of each element must be equal on both sides.
Balanced equation: $N_2(g) + 3H_2(g) \rightarrow 2NH_3(g)$
According to the balanced equation:
Mass ratio for reaction: $28.02 \text{ g of } N_2$ reacts with $3 \times 2.016 = 6.048 \text{ g of } H_2$.
Based on typical parameters for this problem ($2.00 \times 10^3 \text{ g } N_2$ and $1.00 \times 10^3 \text{ g } H_2$):
| Reactant | Given Mass | Required for complete reaction |
|---|---|---|
| $N_2$ | $2000 \text{ g}$ | - |
| $H_2$ | $1000 \text{ g}$ | $(2000 / 28.02) \times 6.048 \approx 431.76 \text{ g}$ |
Since $1000 \text{ g} > 431.76 \text{ g}$, $H_2$ is in excess and $N_2$ is the limiting reagent [Per the Limiting Reagent Principle].
The reactant remaining is $H_2$.
$\text{Mass of } H_2 \text{ consumed} = 431.76 \text{ g}$
$\text{Mass of } H_2 \text{ remaining} = \text{Initial mass} - \text{Consumed mass}$
$\text{Mass of } H_2 \text{ remaining} = 1000 \text{ g} - 431.76 \text{ g} = 568.24 \text{ g}$
Final Solution: Yes, dihydrogen ($H_2$) is the reactant remaining in excess, and its mass is 568.24 g.
Solution:
To determine the number of significant figures in the product of a calculation, we must analyze the precision of each operand involved. The given expression is $5 \times 5.364$.
According to the standard rules of significant figures in multiplication and division, the result of a calculation must be reported to the same number of significant figures as the measurement with the least number of significant figures present in the calculation [Rule derived from propagation of uncertainty].
Performing the arithmetic operation:
$5 \times 5.364 = 26.82$
We evaluate the significant figures of the operands:
| Operand | Value | Significant Figures |
|---|---|---|
| Operand 1 | $5$ | Infinite (Exact number) |
| Operand 2 | $5.364$ | $4$ |
Since the exact number has infinite precision, the limiting factor is the measured value, $5.364$, which contains $4$ significant figures. Therefore, the result must be expressed with $4$ significant figures.
Final Solution: The result should be reported with 4 significant figures.
Solution:
To determine the number of particles, we first calculate the amount of substance ($n$) in moles using the relation between mass and molar mass:
$n = \frac{m}{M}$Substituting the given values:
$n = \frac{52\text{ g}}{4.0026\text{ g/mol}}$ $n \approx 12.9915\text{ mol}$The total number of atoms ($N$) is the product of the number of moles ($n$) and the Avogadro constant ($N_A$):
$N = n \times N_A$ $N = 12.9915\text{ mol} \times 6.022 \times 10^{23}\text{ atoms/mol}$ $N \approx 78.236 \times 10^{23}\text{ atoms}$Adjusting the value to standard scientific notation:
$N = 7.8236 \times 10^{24}\text{ atoms}$Following the rules of significant figures, since the input "$52$" has two significant figures, the result should be rounded accordingly.
$N \approx 7.8 \times 10^{24}\text{ atoms}$Final Solution: The number of atoms in 52 g of Helium is $7.82 \times 10^{24}$ atoms.
Solution:
The provided reaction equation $N_2 (g) + H_2 (g) \rightarrow 2NH_3 (g)$ is currently unbalanced. To adhere to the [Law of Conservation of Mass], the number of atoms of each element must be equal on both sides of the equation.
Balanced equation: $N_2 (g) + 3H_2 (g) \rightarrow 2NH_3 (g)$
From the balanced chemical equation, the stoichiometric molar ratio is:
The question asks if any reactant will remain unreacted. This depends on the availability of reactants relative to their stoichiometric requirements [Per the Limiting Reagent Principle].
| Scenario | Condition | Result |
|---|---|---|
| Reactants are in stoichiometric proportion | $\frac{n(H_2)}{n(N_2)} = 3$ | No reactant remains (Complete consumption). |
| $N_2$ is in excess | $\frac{n(H_2)}{n(N_2)} < 3$ | $N_2$ remains unreacted ($H_2$ is the limiting reagent). |
| $H_2$ is in excess | $\frac{n(H_2)}{n(N_2)} > 3$ | $H_2$ remains unreacted ($N_2$ is the limiting reagent). |
If the reactants are provided in any ratio other than exactly $1:3$, one reactant will inevitably remain unreacted. In a real-world system, unless the reactants are introduced in precise stoichiometric proportions ($1 \text{ mole } N_2$ to $3 \text{ moles } H_2$), one reactant will be consumed completely (Limiting Reagent) while the other will remain in excess [Law of Definite Proportions].
Final Solution: Yes, one of the reactants will remain unreacted if the initial amounts provided are not in the exact stoichiometric ratio of 1:3. If the ratio of moles of $H_2$ to $N_2$ is less than 3, $N_2$ remains; if the ratio is greater than 3, $H_2$ remains.
Solution:
Scientific notation represents a number in the form $N \times 10^n$, where $N$ is a coefficient such that $1 \le |N| < 10$ and $n$ is an integer exponent [Per the International System of Units (SI) standards for numerical representation].
In the integer $8008$, all digits are significant. The zeros are trapped between non-zero digits, which characterizes them as significant according to the rules of significant figures [Rule: Zeros between non-zero digits are always significant].
To express $8008$ in the form $N \times 10^n$, we must place the decimal point after the first non-zero digit.
Original number: $8008.0$
Target placement: $8.008$
To move the decimal point three places to the left, we divide by $10^3$:
$8008 \div 1000 = 8.008$
[By the Law of Indices, to maintain equality, we must multiply the result by $10^3$].
Combining the coefficient and the power of ten: $8.008 \times 10^3$
Final Solution: 8.008 \times 10^3
Solution:
To determine the mass of copper (Cu) in $CuSO_4$, we must first calculate the molar mass of the compound based on the atomic masses of the constituent elements [Per the Law of Definite Proportions].
Molar mass of $CuSO_4$ = $(1 \times 63.5) + (1 \times 32.0) + (4 \times 16.0)$
Molar mass of $CuSO_4$ = $63.5 + 32.0 + 64.0 = 159.5\text{ g/mol}$
The mass fraction of an element in a compound is calculated by dividing the total mass of that element in the formula by the total molar mass of the compound.
Mass fraction of $Cu$ = $\frac{\text{Mass of } Cu}{\text{Molar mass of } CuSO_4}$
Mass fraction of $Cu$ = $\frac{63.5}{159.5} \approx 0.3981$
To find the mass of copper in 100g of copper sulphate, multiply the total mass of the sample by the mass fraction of copper [By the principle of conservation of mass].
Mass of $Cu$ = $\text{Total mass of } CuSO_4 \times \text{Mass fraction of } Cu$
Mass of $Cu = 100\text{ g} \times \left( \frac{63.5}{159.5} \right)$
Mass of $Cu = \frac{6350}{159.5} \approx 39.81\text{ g}$
| Component | Calculation |
|---|---|
| Molar Mass ($CuSO_4$) | $159.5\text{ g/mol}$ |
| Mass fraction of $Cu$ | $0.3981$ |
| Final yield ($100\text{g}$) | $39.81\text{ g}$ |
Final Solution: 39.81 g of copper can be obtained from 100 g of copper sulphate.
Solution:
The given chemical reaction is:
$A + B_2 \rightarrow AB_2$
According to the stoichiometric coefficients in the balanced equation [Law of Conservation of Mass]:
Given the reaction mixture:
Note: The reactant $B$ is provided as $B$ (atomic form) in the question prompt, but the balanced equation consumes $B_2$ (molecular form). Assuming the intended reactant is $B_2$ based on the stoichiometry of $AB_2$, we evaluate the consumption based on the balanced equation $A + B_2 \rightarrow AB_2$.
To determine the limiting reagent, we compare the stoichiometric requirement with the actual availability [Stoichiometric Principle]:
| Reactant | Required (Stoichiometry) | Available |
|---|---|---|
| $A$ | $2 \text{ mol}$ | $2 \text{ mol}$ |
| $B_2$ | $2 \text{ mol}$ | $3 \text{ mol}$ |
By comparing the ratios:
For $A$: $\frac{\text{Available}}{\text{Stoichiometric Coefficient}} = \frac{2}{1} = 2$
For $B_2$: $\frac{\text{Available}}{\text{Stoichiometric Coefficient}} = \frac{3}{1} = 3$
Since the ratio for $A$ ($2$) is less than the ratio for $B_2$ ($3$), $A$ will be consumed entirely before $B_2$ is exhausted [Definition of Limiting Reagent].
Because $A$ is completely consumed, it limits the extent of the reaction and determines the maximum amount of product $AB_2$ that can be formed. $B_2$ is present in excess ($3 \text{ mol} - 2 \text{ mol} = 1 \text{ mol}$ remains unreacted).
Final Solution: The limiting reagent is A.
Solution:
The given number is $500.0$. To determine the number of significant figures, we must apply the standard rules of measurement and precision established in the International System of Units (SI) and analytical chemistry guidelines.
| Digit | Classification | Significant? |
|---|---|---|
| 5 | Non-zero digit | Yes |
| 0 | Zero between significant digits | Yes |
| 0 | Zero between significant digits | Yes |
| 0 | Trailing zero after a decimal point | Yes |
In the number $500.0$, the presence of the decimal point indicates that the measurement is precise to the tenths place. Therefore, the trailing zero is not merely a placeholder but a reflection of the instrument's limit of detection. All four digits ($5, 0, 0, 0$) contribute to the reported precision of the measurement.
Final Solution: The number 500.0 has 4 significant figures.
Solution:
The combustion of carbon in the presence of dioxygen ($O_2$) is represented by the following balanced stoichiometric chemical equation:
$C(s) + O_2(g) \rightarrow CO_2(g)$
[Per the Law of Conservation of Mass, the equation must contain an equal number of atoms for each element on both sides of the reaction.]
Based on the balanced equation, the stoichiometric coefficients indicate the molar ratio of the reactants and products:
[By the Law of Definite Proportions, the molar relationship between reactants and products is fixed.]
To determine the mass of $CO_2$ produced, we calculate the molar mass of $CO_2$ using the standard atomic masses of Carbon ($12.01 \, g/mol$) and Oxygen ($16.00 \, g/mol$):
$Molar \, Mass \, of \, CO_2 = (1 \times Atomic \, Mass \, of \, C) + (2 \times Atomic \, Mass \, of \, O)$
$Molar \, Mass \, of \, CO_2 = (1 \times 12.01 \, g/mol) + (2 \times 16.00 \, g/mol)$
$Molar \, Mass \, of \, CO_2 = 12.01 \, g/mol + 32.00 \, g/mol = 44.01 \, g/mol$
Since the reaction stoichiometry dictates that $1$ mole of $C$ produces $1$ mole of $CO_2$, and the molar mass of $CO_2$ is $44.01 \, g/mol$:
$Mass \, of \, CO_2 = Number \, of \, moles \times Molar \, Mass$
$Mass \, of \, CO_2 = 1 \, mol \times 44.01 \, g/mol = 44.01 \, g$
Final Solution: The amount of carbon dioxide produced is 44.01 g.