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CBSE - Class 12 Physics Atoms Worksheet
explain dalton atomic theory?
The smallest particle of an element that can enter into a chemical combination is
element
b.compound
c.H2O
d.atom
the ______ is the length of the path travelled by light in vaccum during a time interval of 1/299792458 of a second
kilogram
b.second
c.ampere
d.metre
Identify which of the following properties is extensive .
(a) volume
(b) temperature
(c) boiling point
volume
b.temperature
c.volume and temperature
d.boiling point
Calculate these masses.
(a) What is the mass of 6.00 cm3of mercury, density = 13.5939 g/cm3?
(b) What is the mass of 25.0 mL octane, density = 0.702 g/cm3?
81.56kg ,17.55 kg
b.81.56 g , 17.55g
c.81.56 mg, 17.55 mg
d.-81.56g, 17.55g
Worksheet Answers
Solution:
According to J.J. Thomson’s "Plum Pudding" model, the atom is envisioned as a sphere of uniform positive charge density with electrons embedded within it. In this model, the positive charge occupies the entire volume of the atom, which is approximately $10^{-10} \, \text{m}$ in radius. [Per Thomson's historical model]
Ernest Rutherford’s alpha-particle scattering experiment led to the discovery of the atomic nucleus. Rutherford concluded that the positive charge and the bulk of the mass of the atom are concentrated in a tiny central region called the nucleus, with a radius of the order of $10^{-15} \, \text{m}$. The electrons revolve around this nucleus in a vast empty space. Thus, the actual "atomic size" remains the same order of magnitude ($10^{-10} \, \text{m}$), but the distribution of matter differs significantly.
The question asks to compare the "size of the atom" in both models. Based on the experimental outcomes of the gold foil experiment, both models conceptually define the total radius of an atom as approximately $10^{-10} \, \text{m}$.
Since both models attribute the outer boundary of the atom to the extent of the electron cloud, the spatial extent (radius) of the atom in both models is identical. Mathematically, $R_{\text{Thomson}} = R_{\text{Rutherford}} \approx 10^{-10} \, \text{m}$.
| Feature | Thomson Model | Rutherford Model |
|---|---|---|
| Atomic Radius | $\approx 10^{-10} \, \text{m}$ | $\approx 10^{-10} \, \text{m}$ |
| Charge Distribution | Uniform | Centralized (Nucleus) |
Final Solution: The size of the atom in Thomson’s model is the same as the atomic size in Rutherford’s model.
Solution:
To analyze the equilibrium of electrons in atomic models, we must evaluate the force vectors acting upon them. According to Classical Electromagnetic Theory (specifically Maxwell’s equations), an accelerated charge must radiate energy. If an electron were in a "stable equilibrium," it would imply a state where the net force is zero and no energy radiation occurs, preventing the collapse of the atom. In contrast, any orbit characterized by constant change in velocity (acceleration) results in a non-zero net force.
In the Thomson model, the positive charge is distributed uniformly throughout the sphere, and the electron is embedded within it. When the electron is displaced from its equilibrium position at the center, the positive charge distribution exerts a restoring force proportional to the displacement ($F = -kx$). [By Hooke's Law and Electrostatic Force Analysis]. At the center, the net force is zero, representing a position of stable equilibrium.
In the planetary model, electrons revolve around the nucleus in circular orbits. The force acting on the electron is the centripetal force provided by the electrostatic Coulomb force ($F_c = \frac{1}{4\pi\epsilon_0} \frac{Ze^2}{r^2}$). Since the electron is undergoing circular motion, its velocity vector is constantly changing direction. [By Newton’s Second Law of Motion ($F = ma$)], a change in velocity implies a net force directed toward the center of the orbit. Therefore, in the planetary model, the electron is never in equilibrium.
| Model | Force Status | Equilibrium Type |
|---|---|---|
| Thomson (Plum Pudding) | Zero (at center) | Stable Equilibrium |
| Rutherford/Bohr | Non-Zero (Centripetal) | Dynamic (Accelerated) |
The first blank refers to the state where the electron is held by a restoring force in a static potential, characteristic of the Thomson model. The second blank refers to the state of constant acceleration in an orbital path, characteristic of the Rutherford model.
Final Solution: In the ground state of Thomson model electrons are in stable equilibrium, while in Rutherford model electrons always experience a net force.
Solution:
According to the Bohr quantization postulate, the angular momentum ($L$) of a revolving body is quantized and must be an integral multiple of the reduced Planck constant ($\hbar = \frac{h}{2\pi}$). The relationship is expressed as:
$L = mvr = n\frac{h}{2\pi}$
[Per Bohr’s Postulate of Angular Momentum Quantization]
To find the quantum number $n$, we rearrange the equation to solve for $n$:
$n = \frac{2\pi mvr}{h}$
Substitute the given values into the equation:
$n = \frac{2 \times 3.14159 \times (6.0 \times 10^{24}\ \text{kg}) \times (3.0 \times 10^{4}\ \text{m/s}) \times (1.5 \times 10^{11}\ \text{m})}{6.63 \times 10^{-34}\ \text{J}\cdot\text{s}}$
Calculating the numerator:
$\text{Numerator} = 2 \times 3.14159 \times 6.0 \times 3.0 \times 1.5 \times 10^{(24 + 4 + 11)}$
$\text{Numerator} \approx 169.646 \times 10^{39} = 1.696 \times 10^{41}$
Calculating $n$:
$n = \frac{1.696 \times 10^{41}}{6.63 \times 10^{-34}} \approx 0.2558 \times 10^{75} \approx 2.56 \times 10^{74}$
Final Solution: The quantum number characterizing the Earth's revolution is $n \approx 2.56 \times 10^{74}$. This extremely large value indicates that for macroscopic systems, the quantum nature of angular momentum is effectively continuous, aligning with the correspondence principle.
Solution:
According to the Bohr model of the hydrogen atom, the radius of the $n^{th}$ orbit is determined by the quantization of angular momentum. The expression for the radius $r_n$ of the $n^{th}$ orbit is given by:
$r_n = n^2 r_1$
[Per Bohr’s Quantization Postulate: $L = mvr = \frac{nh}{2\pi}$]
Where:
Substituting $n = 2$ into the derived expression:
$r_2 = (2)^2 \times r_1$
$r_2 = 4 \times (5.3 \times 10^{-11} \, \text{m})$
$r_2 = 21.2 \times 10^{-11} \, \text{m}$
$r_2 = 2.12 \times 10^{-10} \, \text{m}$
Substituting $n = 3$ into the derived expression:
$r_3 = (3)^2 \times r_1$
$r_3 = 9 \times (5.3 \times 10^{-11} \, \text{m})$
$r_3 = 47.7 \times 10^{-11} \, \text{m}$
$r_3 = 4.77 \times 10^{-10} \, \text{m}$
| Orbit Number ($n$) | Radius Calculation ($n^2 \times r_1$) | Calculated Radius ($m$) |
|---|---|---|
| 1 | $1^2 \times 5.3 \times 10^{-11}$ | $5.3 \times 10^{-11}$ |
| 2 | $4 \times 5.3 \times 10^{-11}$ | $2.12 \times 10^{-10}$ |
| 3 | $9 \times 5.3 \times 10^{-11}$ | $4.77 \times 10^{-10}$ |
Final Solution: The radius of the $n=2$ orbit is $2.12 \times 10^{-10} \, \text{m}$ and the radius of the $n=3$ orbit is $4.77 \times 10^{-10} \, \text{m}$.
Solution:
According to the Bohr model of the atom, the angular velocity $\omega$ of an electron in a stable orbit is related to the principal quantum number $n$. The orbital period $T$ is defined as the time taken for one complete revolution: $T = \frac{2\pi}{\omega}$.
From the derivation of the Bohr radius ($r_n$) and the velocity ($v_n$), we know that $v_n = \frac{v_1}{n}$ and $r_n = n^2 r_1$. Since $\omega = \frac{v_n}{r_n}$, we substitute the expressions:
$\omega_n = \frac{v_1/n}{n^2 r_1} = \frac{v_1}{n^3 r_1} = \frac{\omega_1}{n^3}$
Thus, the orbital period $T_n$ is given by: $T_n = \frac{2\pi}{\omega_1/n^3} = T_1 \cdot n^3$, where $T_1$ is the period of the ground state ($n=1$). [Per Bohr’s Postulates of Quantization]
For the hydrogen atom, the velocity in the first orbit is $v_1 \approx 2.18 \times 10^6 \text{ m/s}$ and the Bohr radius is $r_1 \approx 0.529 \times 10^{-10} \text{ m}$.
The ground state angular frequency $\omega_1$ is: $\omega_1 = \frac{v_1}{r_1} = \frac{2.18 \times 10^6}{0.529 \times 10^{-10}} \approx 4.12 \times 10^{16} \text{ rad/s}$
Therefore, the ground state period $T_1$ is: $T_1 = \frac{2\pi}{\omega_1} = \frac{2 \times 3.14159}{4.12 \times 10^{16}} \approx 1.52 \times 10^{-16} \text{ s}$
Using the relation $T_n = T_1 \cdot n^3$, we calculate the periods for $n=1, 2, 3$:
| Quantum Number ($n$) | Calculation ($1.52 \times 10^{-16} \times n^3$) | Orbital Period ($T_n$) |
|---|---|---|
| $n=1$ | $1.52 \times 10^{-16} \times 1$ | $1.52 \times 10^{-16} \text{ s}$ |
| $n=2$ | $1.52 \times 10^{-16} \times 8$ | $1.22 \times 10^{-15} \text{ s}$ |
| $n=3$ | $1.52 \times 10^{-16} \times 27$ | $4.10 \times 10^{-15} \text{ s}$ |
Final Solution: The orbital periods for $n=1, 2,$ and $3$ are $1.52 \times 10^{-16} \text{ s}$, $1.22 \times 10^{-15} \text{ s}$, and $4.10 \times 10^{-15} \text{ s}$ respectively.
Solution:
To determine the frequency of the emitted radiation during an electronic transition, we identify the following parameters provided by the problem:
The energy difference must be expressed in Joules ($\text{J}$) to maintain consistency with the SI units of Planck’s constant. [Per the definition of the electronvolt as a unit of energy].
$\Delta E (\text{in Joules}) = 2.3 \text{ eV} \times (1.602 \times 10^{-19} \text{ J/eV})$
$\Delta E = 3.6846 \times 10^{-19} \text{ J}$
According to the Bohr postulate for atomic transitions, the frequency ($\nu$) of the emitted photon is directly proportional to the energy difference between the two states. [Per the Bohr Frequency Condition: $\Delta E = h\nu$].
Rearranging for frequency ($\nu$):
$\nu = \frac{\Delta E}{h}$
Substituting the values calculated in Step 1 and the known constant for Planck's constant:
$\nu = \frac{3.6846 \times 10^{-19} \text{ J}}{6.626 \times 10^{-34} \text{ J}\cdot\text{s}}$
$\nu \approx 0.55608 \times 10^{15} \text{ Hz}$
$\nu \approx 5.56 \times 10^{14} \text{ Hz}$
The transition results in the release of a photon with frequency $\nu$. By applying the relationship $\nu = \frac{\Delta E}{h}$, we establish that the energy gap of $2.3 \text{ eV}$ corresponds to the visible spectrum region (specifically green-yellow light).
Final Solution: The frequency of the emitted radiation is $5.56 \times 10^{14} \text{ Hz}$.
Solution:
According to the Bohr model of the hydrogen atom, the total energy ($E$), kinetic energy ($K$), and potential energy ($U$) of an electron in a stationary orbit are related to the electrostatic interaction between the nucleus (proton) and the orbiting electron [Per the Coulombic Law and Virial Theorem].
The total energy is defined as the sum of kinetic and potential energies:
$E = K + U$
From the virial theorem for a system under an inverse-square law force, we establish the following relationships:
Given the ground state energy $E = -13.6 \text{ eV}$.
Using the derived relation $K = -E$:
$K = -(-13.6 \text{ eV})$
$K = 13.6 \text{ eV}$
[Justification: The kinetic energy must be positive as it represents the work done to bring the electron from rest to its orbital velocity].
Using the derived relation $U = 2E$:
$U = 2 \times (-13.6 \text{ eV})$
$U = -27.2 \text{ eV}$
[Justification: The negative sign indicates that the electron is in a bound state within the electrostatic potential well of the nucleus].
| Parameter | Value (eV) |
|---|---|
| Total Energy ($E$) | $-13.6 \text{ eV}$ |
| Kinetic Energy ($K$) | $+13.6 \text{ eV}$ |
| Potential Energy ($U$) | $-27.2 \text{ eV}$ |
Final Solution: The kinetic energy of the electron in the ground state is 13.6 eV, and the potential energy is -27.2 eV.
Solution:
The energy of an electron in the $n^{th}$ orbit of a hydrogen atom is given by the Bohr formula:
$E_n = -\frac{13.6}{n^2} \, \text{eV}$
The transition energy required to excite an electron from the ground state ($n=1$) to an excited state ($n$) is $\Delta E = E_n - E_1$.
| Orbit ($n$) | Energy ($E_n$ in eV) | Excitation Energy ($\Delta E = E_n - (-13.6)$) |
|---|---|---|
| 1 | -13.6 | 0 eV |
| 2 | -3.4 | 10.2 eV |
| 3 | -1.51 | 12.09 eV |
| 4 | -0.85 | 12.75 eV |
The incident electron beam has an energy of $12.5 \, \text{eV}$.
Since $12.09 \, \text{eV} < 12.5 \, \text{eV} < 12.75 \, \text{eV}$, the hydrogen atoms can be excited up to the $n=3$ energy level. The electrons cannot reach the $n=4$ level because the incident energy is insufficient [Per the Principle of Conservation of Energy].
When the atoms return to the ground state from $n=3$, the following transitions are possible:
Using the relation $\lambda = \frac{hc}{\Delta E}$, where $hc \approx 1240 \, \text{eV}\cdot\text{nm}$:
Final Solution: The series of wavelengths emitted correspond to the Lyman series (102.6 nm and 121.6 nm) and the Balmer series (656.3 nm).