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CBSE - Class 12 Chemistry Haloalkanes and Haloarenes Worksheet

1.
Give the IUPAC names of the following compounds:
(ii) \(CHF_{2}CBrClF\)
2.
How the following conversions can be carried out?
(iv) Toluene to benzyl alcohol
3.

Alkyl fluorides are generally prepared by heating alkyl chlorides with sodium iodide in acetone.

a. True b. False
4.

Write the structure of the major organic product in each of the following reactions:

5.
How will you bring about the following conversions?
(ii) Ethane to bromoethene
6.
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(iii) \(CH_{3}CH_{2}C(CH_{3})_{2}CH_{2}I\)
7.
Give the IUPAC names of the following compounds:
(iii) \(ClCH_{2}C\equiv CCH_{2}Br\)
8.

Write the structure of the major organic product in each of the following reactions:

9.
How the following conversions can be carried out?
(v) Benzene to 4-bromonitrobenzene
10.
How the following conversions can be carried out?
(xvi) 2-Bromopropane to 1-bromopropane
11.
How the following conversions can be carried out?
(vii) Ethanol to propanenitrile
12.
Arrange the compounds of each set in order of reactivity towards \(S_{N}2\) displacement:
(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane
13.
How will you bring about the following conversions?
(ix) 1-Chlorobutane to n-octane
14.
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(ii) \(CH_{3}CH_{2}CH(CH_{3})CH(C_{2}H_{5})Cl\)
15.

Which reagent converts an alkyl chloride into the corresponding alcohol?

a.

NaOH (aqueous)

b.

HCl

c.

NaCl

d.

SOCl?

16.
How will you bring about the following conversions?
(viii) But-1-ene to but-2-ene
17.
How the following conversions can be carried out?
(xv) Chlorobenzene to p-nitrophenol
18.
Arrange the compounds of each set in order of reactivity towards \(S_{N}2\) displacement:
(i) 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
19.
Give the IUPAC names of the following compounds:
(i) \(CH_{3}CH(Cl)CH(Br)CH_{3}\)
20.
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(i) \((CH_{3})_{2}CHCH(Cl)CH_{3}\)

Worksheet Answers

3.
Option B
15.
Option A

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