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Lesson Posted on 08 May Learn Unit XII: Aldehydes, Ketones and Carboxylic Acids
Chemistry, oxidation of ketones
Monika Katoch
Experienced chemistry teacher with 6+ years of experience teaching at the high school and Senior Secondary...
Oxidation of ketones is carried by strong oxidizing agent like concentrated HNO3, KmNO4/H2SO4, dil K2Cr 2O7/H2SO4
For eg
CH3COCH2CH3 +Conc. HNO3= CH3COOH + CH3COOH
CH3COCH2CH2CH3 + conc.HNO3 = CH3COOH + CH3CH2COOH.
Breaking of C ---CO bond takes place according to —poppof's rule
Which states that carbonyl group stays together with smaller alkyl group.
read lessAnswered on 13 Apr Learn Unit I: Relations and Functions
Nazia Khanum
A relation R:A→AR:A→A is said to be reflexive if, for every element aa in the set AA (where AA is a non-empty set), the ordered pair (a,a)(a,a) belongs to the relation RR. In simpler terms, reflexive relations include every element paired with itself in the set.
Answered on 13 Apr Learn Unit I: Relations and Functions
Nazia Khanum
A relation R:A→AR:A→A is said to be symmetric if for every pair of elements a,ba,b in set AA, whenever (a,b)(a,b) is in RR, then (b,a)(b,a) must also be in RR. In other words, if aa is related to bb, then bb must be related to aa as well, for all a,ba,b in AA.
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Answered on 13 Apr Learn Unit I: Relations and Functions
Nazia Khanum
A universal relation in the context of relational databases refers to a relation (or table) that contains all possible combinations of tuples from the sets involved. In simpler terms, it includes every possible pair of elements from its constituent sets.
For example, let's consider a universal relation that represents the Cartesian product of the sets A = {1, 2} and B = {x, y}. The universal relation would contain all possible combinations of elements from A and B:
Universal Relation: (1, x) (1, y) (2, x) (2, y)
In this example, the universal relation contains all possible combinations of elements from set A and set B.
read lessAnswered on 13 Apr Learn Unit I: Relations and Functions
Nazia Khanum
To prove that the function f:R→Rf:R→R given by f(x)=2xf(x)=2x is one-to-one (injective), we need to show that if f(x1)=f(x2)f(x1)=f(x2), then x1=x2x1=x2 for all x1,x2x1,x2 in the domain.
Let's assume f(x1)=f(x2)f(x1)=f(x2): 2x1=2x22x1=2x2
Now, we'll solve for x1x1 and x2x2: x1=x2x1=x2
Since x1=x2x1=x2, it means that for any two inputs x1x1 and x2x2 that produce the same output under the function f(x)=2xf(x)=2x, those inputs must be the same. This proves that the function f(x)=2xf(x)=2x is one-to-one.
Answered on 13 Apr Learn Unit I: Relations and Functions
Nazia Khanum
To prove that (f+g)∘h=f∘h+g∘h(f+g)∘h=f∘h+g∘h, let's start by understanding what (f+g)∘h(f+g)∘h means:
(f+g)∘h(x)=(f+g)(h(x))=f(h(x))+g(h(x))(f+g)∘h(x)=(f+g)(h(x))=f(h(x))+g(h(x))
Now, let's find (f∘h+g∘h)(x)(f∘h+g∘h)(x):
f∘h(x)+g∘h(x)=f(h(x))+g(h(x))f∘h(x)+g∘h(x)=f(h(x))+g(h(x))
This expression is identical to what we found for (f+g)∘h(x)(f+g)∘h(x). Hence, we can conclude that (f+g)∘h=f∘h+g∘h(f+g)∘h=f∘h+g∘h.
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Answered on 13 Apr Learn Unit I: Relations and Functions
Nazia Khanum
To find (g∘f)(x)(g∘f)(x), which is the composition of g(x)g(x) with f(x)f(x), we substitute f(x)f(x) into g(x)g(x) wherever we see xx.
Given:
f(x)=∣x∣f(x)=∣x∣ g(x)=∣5x+1∣g(x)=∣5x+1∣
We first find f(x)f(x):
f(x)=∣x∣f(x)=∣x∣
And then substitute it into g(x)g(x):
g(f(x))=∣5(∣x∣)+1∣g(f(x))=∣5(∣x∣)+1∣
Now, ∣x∣∣x∣ can be either xx if x≥0x≥0 or −x−x if x<0x<0.
So, ∣5(∣x∣)+1∣∣5(∣x∣)+1∣ will be:
If x≥0x≥0: g(f(x))=∣5x+1∣g(f(x))=∣5x+1∣
If x<0x<0: g(f(x))=∣−5x+1∣g(f(x))=∣−5x+1∣
Answered on 13 Apr Learn Unit VII: p - Block Elements
Nazia Khanum
Nitrogen dioxide (NO2NO2) dimerizes to form dinitrogen tetroxide (N2O4N2O4) due to the presence of unpaired electrons on each nitrogen atom in the NO2NO2 molecule. This dimerization process is a result of the tendency of molecules with unpaired electrons to pair up and form more stable configurations.
In the gas phase, NO2NO2 exists predominantly as a reddish-brown dimer, N2O4N2O4, which is colorless. The dimerization reaction can be represented as:
2NO2⇌N2O42NO2⇌N2O4
This process is reversible, meaning that N2O4N2O4 can dissociate back into NO2NO2 molecules. The equilibrium between NO2NO2 and N2O4N2O4 depends on factors such as temperature, pressure, and concentration.
The dimerization of NO2NO2 to form N2O4N2O4 is an important reaction in atmospheric chemistry. In polluted urban environments, NO2NO2 is often emitted from vehicles and industrial sources. When NO2NO2 reacts with other pollutants and undergoes dimerization to form N2O4N2O4, it can contribute to the formation of smog and other harmful atmospheric conditions.
Answered on 13 Apr Learn Unit VIII: d and f Block Elements
Nazia Khanum
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Answered on 13 Apr Learn Unit IX: Coordination Compounds
Nazia Khanum
The complex Co(NH3)5(NO2)2 exhibits two types of isomerism:
Coordination Isomerism: Coordination isomers occur when the ligands in a complex exchange places with anionic or neutral ligands outside the coordination sphere. In this complex, NO2 and NO3 can interchange positions, leading to the formation of coordination isomers.
Ionization Isomerism: Ionization isomers arise when there's a difference in the location of a ligand within a complex or between an ion and a molecule. In this case, the NO3^- ions in the coordination sphere can exchange positions with the NO3^- ions outside the coordination sphere.
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