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CBSE - Class 12 Chemistry Aldehydes Worksheet

1.

In terms of relative acid strength, which of these acids is the strongest?

a.

Acetic acid 

b.

Propionic acid 

c.

Iso propionic acid 

d.

Benzoic acid 

2.
Draw structures of the following derivatives.
(iii) Acetaldehydedimethylacetal
3.
Arrange the following compounds in increasing order of their property as indicated:
(ii) \(CH_{3}CH_{2}CH(Br)COOH\), \(CH_{3}CH(Br)CH_{2}COOH\), \((CH_{3})_{2}CHCOOH\), \(CH_{3}CH_{2}CH_{2}COOH\) (acid strength)
4.
Draw the structures of the following compounds.
(viii) Hex-2-en-4-ynoic acid
5.
Name the following compounds according to IUPAC system of nomenclature:
(iii) \(CH_{3}CH=CHCHO\)
6.
Describe the following:
(iv) Decarboxylation
7.
Arrange the following compounds in increasing order of their property as indicated:
(iii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid strength)
8.
Which of the following compounds would undergo aldol condensation, which the Cannizzaro reaction and which neither? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.
(vi) 1-Phenylpropanone
9.
Describe the following:
(ii) Cannizzaro reaction
10.
Name the following compounds according to IUPAC system of nomenclature:
(ii) \(CH_{3}CH_{2}COCH(C_{2}H_{5})CH_{2}CH_{2}Cl\)
11.
Draw structures of the following derivatives.
(v) The ethylene ketal of hexan-3-one
12.
Give simple chemical tests to distinguish between the following pairs of compounds.
(i) Propanal and Propanone
13.
Draw the structures of the following compounds.
(v) 4-Chloropentan-2-one
14.
How will you bring about the following conversions in not more than two steps?
(vi) Bromobenzene to 1-Phenylethanol
15.
Predict the products formed when cyclohexanecarbaldehyde reacts with following reagents.
(v) Zinc amalgam and dilute hydrochloric acid
16.
Describe the following:
(i) Acetylation
17.

Complete each synthesis by giving missing starting material, reagent or products.

18.
What is meant by the following terms ? Give an example of the reaction in each case.
(v) Hemiacetal
19.
Draw the structures of the following compounds.
(vi) 3-Bromo-4-phenylpentanoic acid
20.
Name the following compounds according to IUPAC system of nomenclature:
(i) \(CH_{3}CH(CH_{3})CH_{2}CH_{2}CHO\)

Worksheet Answers

1.
Option D

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